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Antiferromagnetic interactions arising from a close contact between nitroxyl oxygen and β-methyl carbon atoms carrying an α-spin in the solid state

Yoshiaki Uchida 1
Yoshiaki Uchida
, 
Rui Tamura 1, 2
Rui Tamura
, 
Naohiko Ikuma 2
Naohiko Ikuma
, 
Kazuyoshi Masaki 1
Kazuyoshi Masaki
, 
Hiroki Takahashi 1
Hiroki Takahashi
, 
Satoshi Shimono 3
Satoshi Shimono
, 
Jun Yamauchi 3
Jun Yamauchi
10.1070/MC2006v016n02ABEH002231
Published 2006-04-14
Communication , Volume 16, Issue 2, 69-71
7
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Uchida Y. et al. Antiferromagnetic interactions arising from a close contact between nitroxyl oxygen and β-methyl carbon atoms carrying an α-spin in the solid state // Mendeleev Communications. 2006. Vol. 16. No. 2. pp. 69-71.
GOST all authors (up to 50) Copy
Uchida Y., Tamura R., Ikuma N., Masaki K., Takahashi H., Shimono S., Yamauchi J. Antiferromagnetic interactions arising from a close contact between nitroxyl oxygen and β-methyl carbon atoms carrying an α-spin in the solid state // Mendeleev Communications. 2006. Vol. 16. No. 2. pp. 69-71.
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TY - JOUR
DO - 10.1070/MC2006v016n02ABEH002231
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002231
TI - Antiferromagnetic interactions arising from a close contact between nitroxyl oxygen and β-methyl carbon atoms carrying an α-spin in the solid state
T2 - Mendeleev Communications
AU - Uchida, Yoshiaki
AU - Tamura, Rui
AU - Ikuma, Naohiko
AU - Masaki, Kazuyoshi
AU - Takahashi, Hiroki
AU - Shimono, Satoshi
AU - Yamauchi, Jun
PY - 2006
DA - 2006/04/14
PB - Mendeleev Communications
SP - 69-71
IS - 2
VL - 16
ER -
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@article{2006_Uchida,
author = {Yoshiaki Uchida and Rui Tamura and Naohiko Ikuma and Kazuyoshi Masaki and Hiroki Takahashi and Satoshi Shimono and Jun Yamauchi},
title = {Antiferromagnetic interactions arising from a close contact between nitroxyl oxygen and β-methyl carbon atoms carrying an α-spin in the solid state},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002231},
number = {2},
pages = {69--71},
doi = {10.1070/MC2006v016n02ABEH002231}
}
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Uchida, Yoshiaki, et al. “Antiferromagnetic interactions arising from a close contact between nitroxyl oxygen and β-methyl carbon atoms carrying an α-spin in the solid state.” Mendeleev Communications, vol. 16, no. 2, Apr. 2006, pp. 69-71. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002231.

Abstract

Antiferromagnetic interactions (|J|/kB > 4.0), which were observed by the magnetization measurement of the powder samples of the racemic nitroxyl radicals trans-2,5-bis(4-methylphenyl)-2,5-dimethylpyrrolidine-1-oxy [(±)-1a] and trans-2,5-bis(4-bromophenyl)-2,5-dimethylpyrrolidine-1-oxy [(±)-2a] at low temperatures, were rationalised in terms of the intermolecular spin polarization exchange coupling or the SOMO–SOMO overlapping owing to a short contact between the nitroxyl oxygen atom and the β-carbon atom of a neighbouring molecule by X-ray crystallographic analysis and DFT calculations.

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