Home / Publications / Synthesis of 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-1H-pyridine-3,4,4-tricarbonitriles by the reaction of tetracyanoethylene with aldehydes

Synthesis of 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-1H-pyridine-3,4,4-tricarbonitriles by the reaction of tetracyanoethylene with aldehydes

, 
Sergey Nikolaevich Molkov 1
Sergey Nikolaevich Molkov
, 
Oleg Vyacheslavovich Ershov 1
Oleg Vyacheslavovich Ershov
, 
Yakov Sergeyevich Kayukov 1
Yakov Sergeyevich Kayukov
, 
Oleg Evgenevich Nasakin 1
Oleg Evgenevich Nasakin
, 
Victor Aleksandrovich Tafeenko 2
Victor Aleksandrovich Tafeenko
, 
Evgeniya Vladimirovna Nurieva 2
Evgeniya Vladimirovna Nurieva
10.1070/MC2006v016n02ABEH002206
Published 2006-04-14
Communication , Volume 16, Issue 2, 115-117
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Eremkin A. V. et al. Synthesis of 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-1H-pyridine-3,4,4-tricarbonitriles by the reaction of tetracyanoethylene with aldehydes // Mendeleev Communications. 2006. Vol. 16. No. 2. pp. 115-117.
GOST all authors (up to 50) Copy
Eremkin A. V., Molkov S. N., Ershov O. V., Kayukov Y. S., Nasakin O. E., Tafeenko V. A., Nurieva E. V. Synthesis of 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-1H-pyridine-3,4,4-tricarbonitriles by the reaction of tetracyanoethylene with aldehydes // Mendeleev Communications. 2006. Vol. 16. No. 2. pp. 115-117.
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TY - JOUR
DO - 10.1070/MC2006v016n02ABEH002206
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002206
TI - Synthesis of 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-1H-pyridine-3,4,4-tricarbonitriles by the reaction of tetracyanoethylene with aldehydes
T2 - Mendeleev Communications
AU - Eremkin, Aleksei Vladimirovich
AU - Molkov, Sergey Nikolaevich
AU - Ershov, Oleg Vyacheslavovich
AU - Kayukov, Yakov Sergeyevich
AU - Nasakin, Oleg Evgenevich
AU - Tafeenko, Victor Aleksandrovich
AU - Nurieva, Evgeniya Vladimirovna
PY - 2006
DA - 2006/04/14
PB - Mendeleev Communications
SP - 115-117
IS - 2
VL - 16
ER -
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@article{2006_Eremkin,
author = {Aleksei Vladimirovich Eremkin and Sergey Nikolaevich Molkov and Oleg Vyacheslavovich Ershov and Yakov Sergeyevich Kayukov and Oleg Evgenevich Nasakin and Victor Aleksandrovich Tafeenko and Evgeniya Vladimirovna Nurieva},
title = {Synthesis of 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-1H-pyridine-3,4,4-tricarbonitriles by the reaction of tetracyanoethylene with aldehydes},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002206},
number = {2},
pages = {115--117},
doi = {10.1070/MC2006v016n02ABEH002206}
}
MLA
Cite this
MLA Copy
Eremkin, Aleksei Vladimirovich, et al. “Synthesis of 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-1H-pyridine-3,4,4-tricarbonitriles by the reaction of tetracyanoethylene with aldehydes.” Mendeleev Communications, vol. 16, no. 2, Apr. 2006, pp. 115-117. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002206.

Abstract

The reaction of tetracyanoethylene and isobutyraldehyde or 2-ethylbutanal in an excess of a hydrohalogen acid yields 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-3,4,4(1H)-pyridinetricarbonitriles, the crystal and molecular structures of which were characterised by IR, NMR, MS and X-ray analysis.

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