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Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene

Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
, 
Ludmila Andreevna Oparina 1
Ludmila Andreevna Oparina
, 
Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
, 
Marina Yakovlevna Khil'ko 1
Marina Yakovlevna Khil'ko
, 
Lidiya Nikiforovna Parshina 1
Lidiya Nikiforovna Parshina
, 
Jochem Henkelmann 2
Jochem Henkelmann
10.1070/MC2006v016n01ABEH002198
Published 2006-01-31
Communication , Volume 16, Issue 1, 13-14
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Trofimov B. A. et al. Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene // Mendeleev Communications. 2006. Vol. 16. No. 1. pp. 13-14.
GOST all authors (up to 50) Copy
Trofimov B. A., Oparina L. A., Gusarova N. K., Khil'ko M. Y., Parshina L. N., Henkelmann J. Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene // Mendeleev Communications. 2006. Vol. 16. No. 1. pp. 13-14.
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TY - JOUR
DO - 10.1070/MC2006v016n01ABEH002198
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n01ABEH002198
TI - Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene
T2 - Mendeleev Communications
AU - Trofimov, Boris Aleksandrovich
AU - Oparina, Ludmila Andreevna
AU - Gusarova, Nina Kuzminichna
AU - Khil'ko, Marina Yakovlevna
AU - Parshina, Lidiya Nikiforovna
AU - Henkelmann, Jochem
PY - 2006
DA - 2006/01/31
PB - Mendeleev Communications
SP - 13-14
IS - 1
VL - 16
ER -
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@article{2006_Trofimov,
author = {Boris Aleksandrovich Trofimov and Ludmila Andreevna Oparina and Nina Kuzminichna Gusarova and Marina Yakovlevna Khil'ko and Lidiya Nikiforovna Parshina and Jochem Henkelmann},
title = {Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n01ABEH002198},
number = {1},
pages = {13--14},
doi = {10.1070/MC2006v016n01ABEH002198}
}
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Trofimov, Boris Aleksandrovich, et al. “Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene.” Mendeleev Communications, vol. 16, no. 1, Jan. 2006, pp. 13-14. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n01ABEH002198.

Abstract

In the superbase catalytic systems ButOK/NMP, AmtOCs/NMP and KOH/DMSO, methanol readily adds to propyne and allene at 100–120 °C and atmospheric pressure to afford 2-methoxypropene in 80–97% yield with 75–94% methanol conversion.

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