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Spin–spin exchange interactions in a binuclear tetra-pivalate bridged manganese(II) complex

Yury V Rakitin 1
Yury V Rakitin
, 
Vladimir Mikhailovich Novotortsev 2
Vladimir Mikhailovich Novotortsev
, 
Vladimir Nikolaevich Ikorskii 3
Vladimir Nikolaevich Ikorskii
, 
1 I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Raw Mineral Materials, Kol'skii Scientific Centre of the Russian Academy of Sciences, Apatity
10.1070/MC2006v016n01ABEH002162
Published 2006-01-31
Communication , Volume 16, Issue 1, 23-24
2
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Rakitin Y. V. et al. Spin–spin exchange interactions in a binuclear tetra-pivalate bridged manganese(II) complex // Mendeleev Communications. 2006. Vol. 16. No. 1. pp. 23-24.
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Rakitin Y. V., Novotortsev V. M., Ikorskii V. N., Eremenko I. L. Spin–spin exchange interactions in a binuclear tetra-pivalate bridged manganese(II) complex // Mendeleev Communications. 2006. Vol. 16. No. 1. pp. 23-24.
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TY - JOUR
DO - 10.1070/MC2006v016n01ABEH002162
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n01ABEH002162
TI - Spin–spin exchange interactions in a binuclear tetra-pivalate bridged manganese(II) complex
T2 - Mendeleev Communications
AU - Rakitin, Yury V
AU - Novotortsev, Vladimir Mikhailovich
AU - Ikorskii, Vladimir Nikolaevich
AU - Eremenko, Igor Leonidovich
PY - 2006
DA - 2006/01/31
PB - Mendeleev Communications
SP - 23-24
IS - 1
VL - 16
ER -
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@article{2006_Rakitin,
author = {Yury V Rakitin and Vladimir Mikhailovich Novotortsev and Vladimir Nikolaevich Ikorskii and Igor Leonidovich Eremenko},
title = {Spin–spin exchange interactions in a binuclear tetra-pivalate bridged manganese(II) complex},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n01ABEH002162},
number = {1},
pages = {23--24},
doi = {10.1070/MC2006v016n01ABEH002162}
}
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Rakitin, Yury V., et al. “Spin–spin exchange interactions in a binuclear tetra-pivalate bridged manganese(II) complex.” Mendeleev Communications, vol. 16, no. 1, Jan. 2006, pp. 23-24. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n01ABEH002162.

Abstract

The magnetic properties of a MnII dimer L2Mn2(μ-OOCCMe3)4 (L = 2,6-diaminopyridine) can be correctly described with allowance for isotropic bilinear (−2J1 = 16.5 cm−1) and biquadratic (−2J2 = 0.49 cm−1) exchange, the latter crucially influencing the magnetic susceptibility in the whole temperature range.

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