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Chemistry of O- and C-adducts derived from 1,4-diazinium salts: the use of tetrahydropyrazines in the synthesis of condensed systems

Gennady Leonidovich Rusinov 1
Gennady Leonidovich Rusinov
, 
Pavel Alexandrovich Slepukhin 1
Pavel Alexandrovich Slepukhin
,  , 
Oleg Anatol'evich Dyachenko 2
Oleg Anatol'evich Dyachenko
, 
Olga Nikolaevna Kazheva 2
Olga Nikolaevna Kazheva
, 
Anatolii Nikolaevich Chekhlov 2
Anatolii Nikolaevich Chekhlov
,  , 
Mikhail Isaakovich Kodess 1
Mikhail Isaakovich Kodess
, 
Oleg Nikolaevich Chupakhin 1
Oleg Nikolaevich Chupakhin
10.1070/MC2006v016n01ABEH002153
Published 31 January 2006 , received 22 August 2005
Communication , Volume 16, Issue 1, 26-29
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Rusinov G. L. et al. Chemistry of O- and C-adducts derived from 1,4-diazinium salts: the use of tetrahydropyrazines in the synthesis of condensed systems // Mendeleev Communications. 2006. Vol. 16. No. 1. pp. 26-29.
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Rusinov G. L., Slepukhin P. A., Charushin V. N., Dyachenko O. A., Kazheva O. N., Chekhlov A. N., Verbitskiy E. V., Kodess M. I., Chupakhin O. N. Chemistry of O- and C-adducts derived from 1,4-diazinium salts: the use of tetrahydropyrazines in the synthesis of condensed systems // Mendeleev Communications. 2006. Vol. 16. No. 1. pp. 26-29.
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TY - JOUR
DO - 10.1070/MC2006v016n01ABEH002153
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n01ABEH002153
TI - Chemistry of O- and C-adducts derived from 1,4-diazinium salts: the use of tetrahydropyrazines in the synthesis of condensed systems
T2 - Mendeleev Communications
AU - Rusinov, Gennady Leonidovich
AU - Slepukhin, Pavel Alexandrovich
AU - Charushin, Valery Nikolaevich
AU - Dyachenko, Oleg Anatol'evich
AU - Kazheva, Olga Nikolaevna
AU - Chekhlov, Anatolii Nikolaevich
AU - Verbitskiy, Egor Vladimirovich
AU - Kodess, Mikhail Isaakovich
AU - Chupakhin, Oleg Nikolaevich
PY - 2006
DA - 2006/01/31
PB - Mendeleev Communications
SP - 26-29
IS - 1
VL - 16
ER -
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@article{2006_Rusinov,
author = {Gennady Leonidovich Rusinov and Pavel Alexandrovich Slepukhin and Valery Nikolaevich Charushin and Oleg Anatol'evich Dyachenko and Olga Nikolaevna Kazheva and Anatolii Nikolaevich Chekhlov and Egor Vladimirovich Verbitskiy and Mikhail Isaakovich Kodess and Oleg Nikolaevich Chupakhin},
title = {Chemistry of O- and C-adducts derived from 1,4-diazinium salts: the use of tetrahydropyrazines in the synthesis of condensed systems},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n01ABEH002153},
number = {1},
pages = {26--29},
doi = {10.1070/MC2006v016n01ABEH002153}
}
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Rusinov, Gennady Leonidovich, et al. “Chemistry of O- and C-adducts derived from 1,4-diazinium salts: the use of tetrahydropyrazines in the synthesis of condensed systems.” Mendeleev Communications, vol. 16, no. 1, Jan. 2006, pp. 26-29. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n01ABEH002153.
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Abstract

1-Ethyl-2,3-dicyano-5-nitromethyl-6-methoxy-1,4,5,6-tetrahydropyrazine reacts with N-methylquinoxalinium iodide in the presence of triethylamine to form octahydro-2,4a,5,10-tetraazabenzo[b]fluorene-3,4-dicarbonitrile, while our attempts to obtain similar polycyclic products from stereoisomeric 5-(S)- and 5-(R)-(1′-nitroprop-1′-yl)-6-methoxy-1,4,5,6-tetrahydropyrazines derived from the reaction of 1-nitropropane with 2,3-dicyano-5,6-dimethoxy-1-ethyl-1,4,5,6-tetrahydropyrazine.

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