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Rearrangement of the siloxane skeleton in Cu–Na-containing phenylsiloxanes

Boris Grigor'evich Zavin 1
Boris Grigor'evich Zavin
, 
Natalya Vasil'evna Sergienko 1
Natalya Vasil'evna Sergienko
, 
Eugene Vladimirovich Gorodnichev 1
Eugene Vladimirovich Gorodnichev
, 
Victor Davidovich Myakushev 2
Victor Davidovich Myakushev
, 
Alexander Aleksandrovich Korlyukov 1
Alexander Aleksandrovich Korlyukov
, 
Mikhail Yuvenal'evich Antipin 1
Mikhail Yuvenal'evich Antipin
10.1070/MC2005v015n06ABEH002191
Published 2005-11-24
Communication , Volume 15, Issue 6, 245-246
9
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Zavin B. G. et al. Rearrangement of the siloxane skeleton in Cu–Na-containing phenylsiloxanes // Mendeleev Communications. 2005. Vol. 15. No. 6. pp. 245-246.
GOST all authors (up to 50) Copy
Zavin B. G., Sergienko N. V., Gorodnichev E. V., Myakushev V. D., Korlyukov A. A., Antipin M. Y. Rearrangement of the siloxane skeleton in Cu–Na-containing phenylsiloxanes // Mendeleev Communications. 2005. Vol. 15. No. 6. pp. 245-246.
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TY - JOUR
DO - 10.1070/MC2005v015n06ABEH002191
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n06ABEH002191
TI - Rearrangement of the siloxane skeleton in Cu–Na-containing phenylsiloxanes
T2 - Mendeleev Communications
AU - Zavin, Boris Grigor'evich
AU - Sergienko, Natalya Vasil'evna
AU - Gorodnichev, Eugene Vladimirovich
AU - Myakushev, Victor Davidovich
AU - Korlyukov, Alexander Aleksandrovich
AU - Antipin, Mikhail Yuvenal'evich
PY - 2005
DA - 2005/11/24
PB - Mendeleev Communications
SP - 245-246
IS - 6
VL - 15
ER -
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@article{2005_Zavin,
author = {Boris Grigor'evich Zavin and Natalya Vasil'evna Sergienko and Eugene Vladimirovich Gorodnichev and Victor Davidovich Myakushev and Alexander Aleksandrovich Korlyukov and Mikhail Yuvenal'evich Antipin},
title = {Rearrangement of the siloxane skeleton in Cu–Na-containing phenylsiloxanes},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n06ABEH002191},
number = {6},
pages = {245--246},
doi = {10.1070/MC2005v015n06ABEH002191}
}
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Zavin, Boris Grigor'evich, et al. “Rearrangement of the siloxane skeleton in Cu–Na-containing phenylsiloxanes.” Mendeleev Communications, vol. 15, no. 6, Nov. 2005, pp. 245-246. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n06ABEH002191.

Abstract

The conversion of ‘sandwich’-like metalophenylsiloxane [PhSiO2]6Cu4Na4[PhSiO2]6 to ‘horse saddle’-like [PhSiO2]12Cu4Na4 was settled; this is the first example of chemical transformation of cage-like metalorganosiloxanes that occurs with rearrangement of Si–O–Si skeleton bonds and with the retaining of the cluster Cu4Na4.

References

1.
10.1070/MC2005v015n06ABEH002191_bib1
Ovchinnikov
Izv. Akad. Nauk SSSR, Ser. Khim., 1986
2.
Novel class of transition metal coordination compounds with macrocyclic organosiloxanolate ligands; their synthesis and crystal structure
Igonin V.A., Shchegolikhina O.I., Lindeman S.V., Levitsky M.M., Struchkov Y.T., Zhdanov A.A.
Journal of Organometallic Chemistry, 1992
3.
10.1070/MC2005v015n06ABEH002191_bib3
Igonin
Izv. Akad. Nauk, Ser. Khim., 1993
4.
10.1070/MC2005v015n06ABEH002191_bib4
Igonin
Metalloorg. Khim., 1991
5.
10.1070/MC2005v015n06ABEH002191_bib5
Molodtsova
Izv. Akad. Nauk, Ser. Khim., 2003
6.
E. S. Trankina, Khimicheskie reaktsii v karkasnykh i polimernykh metallosiloksanakh (Chemical Reactions in Framework and Polymer Metallosiloxanes), PhD Thesis, Moscow, 2003. in press.
7.
10.1070/MC2005v015n06ABEH002191_bib7
Zhdanov
Izv. Akad. Nauk, Ser. Khim., 1998
8.
10.1070/MC2005v015n06ABEH002191_bib8
Blagodatskikh
Izv. Akad. Nauk, Ser. Khim., 1994
9.
10.1070/MC2005v015n06ABEH002191_bib9
Shchegolikhina
Dokl. Akad. Nauk, 1992