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Synthesis of trifluoromethyl-containing depsipeptides via OH insertion of rhodium carbenoid into the carboxylic group of N-protected α-amino acids

Daria Vladimirovna Vorobyeva 1
Daria Vladimirovna Vorobyeva
, 
Igor Dem'yanovich Titanyuk 2
Igor Dem'yanovich Titanyuk
,  , 
Sergey Nikolaevich Osipov 1
Sergey Nikolaevich Osipov
10.1070/MC2005v015n06ABEH002187
Published 2005-11-24
Communication , Volume 15, Issue 6, 222-223
13
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Vorobyeva D. V. et al. Synthesis of trifluoromethyl-containing depsipeptides via OH insertion of rhodium carbenoid into the carboxylic group of N-protected α-amino acids // Mendeleev Communications. 2005. Vol. 15. No. 6. pp. 222-223.
GOST all authors (up to 50) Copy
Vorobyeva D. V., Titanyuk I. D., Beletskaya I. P., Osipov S. N. Synthesis of trifluoromethyl-containing depsipeptides via OH insertion of rhodium carbenoid into the carboxylic group of N-protected α-amino acids // Mendeleev Communications. 2005. Vol. 15. No. 6. pp. 222-223.
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TY - JOUR
DO - 10.1070/MC2005v015n06ABEH002187
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n06ABEH002187
TI - Synthesis of trifluoromethyl-containing depsipeptides via OH insertion of rhodium carbenoid into the carboxylic group of N-protected α-amino acids
T2 - Mendeleev Communications
AU - Vorobyeva, Daria Vladimirovna
AU - Titanyuk, Igor Dem'yanovich
AU - Beletskaya, Irina Petrovna
AU - Osipov, Sergey Nikolaevich
PY - 2005
DA - 2005/11/24
PB - Mendeleev Communications
SP - 222-223
IS - 6
VL - 15
ER -
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@article{2005_Vorobyeva,
author = {Daria Vladimirovna Vorobyeva and Igor Dem'yanovich Titanyuk and Irina Petrovna Beletskaya and Sergey Nikolaevich Osipov},
title = {Synthesis of trifluoromethyl-containing depsipeptides via OH insertion of rhodium carbenoid into the carboxylic group of N-protected α-amino acids},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n06ABEH002187},
number = {6},
pages = {222--223},
doi = {10.1070/MC2005v015n06ABEH002187}
}
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Vorobyeva, Daria Vladimirovna, et al. “Synthesis of trifluoromethyl-containing depsipeptides via OH insertion of rhodium carbenoid into the carboxylic group of N-protected α-amino acids.” Mendeleev Communications, vol. 15, no. 6, Nov. 2005, pp. 222-223. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n06ABEH002187.
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Abstract

A new approach to trifluoromethyl-depsipeptides involving the formation of a COO–CH(CF3)CO link by a metal carbene insertion reaction into the COOH group of N-protected amino acids has been developed.

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