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Microwave-assisted dry oxidation of 3-trialkylsilyl(germyl)prop-2-yn-1-ols to propynals and the direct conversion of acetylenic alcohols to ynimines and enynes

Alexander Vladimirovich Mareev 1
Alexander Vladimirovich Mareev
, 
Alevtina Sergeevna Medvedeva 1
Alevtina Sergeevna Medvedeva
, 
Alexander Voroshilovich Khatashkeev 1
Alexander Voroshilovich Khatashkeev
, 
Andrei Valer'evich Afonin 1
Andrei Valer'evich Afonin
10.1070/MC2005v015n06ABEH002008
Published 2005-11-24
Communication , Volume 15, Issue 6, 263-265
7
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Mareev A. V. et al. Microwave-assisted dry oxidation of 3-trialkylsilyl(germyl)prop-2-yn-1-ols to propynals and the direct conversion of acetylenic alcohols to ynimines and enynes // Mendeleev Communications. 2005. Vol. 15. No. 6. pp. 263-265.
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Mareev A. V., Medvedeva A. S., Khatashkeev A. V., Afonin A. V. Microwave-assisted dry oxidation of 3-trialkylsilyl(germyl)prop-2-yn-1-ols to propynals and the direct conversion of acetylenic alcohols to ynimines and enynes // Mendeleev Communications. 2005. Vol. 15. No. 6. pp. 263-265.
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TY - JOUR
DO - 10.1070/MC2005v015n06ABEH002008
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n06ABEH002008
TI - Microwave-assisted dry oxidation of 3-trialkylsilyl(germyl)prop-2-yn-1-ols to propynals and the direct conversion of acetylenic alcohols to ynimines and enynes
T2 - Mendeleev Communications
AU - Mareev, Alexander Vladimirovich
AU - Medvedeva, Alevtina Sergeevna
AU - Khatashkeev, Alexander Voroshilovich
AU - Afonin, Andrei Valer'evich
PY - 2005
DA - 2005/11/24
PB - Mendeleev Communications
SP - 263-265
IS - 6
VL - 15
ER -
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@article{2005_Mareev,
author = {Alexander Vladimirovich Mareev and Alevtina Sergeevna Medvedeva and Alexander Voroshilovich Khatashkeev and Andrei Valer'evich Afonin},
title = {Microwave-assisted dry oxidation of 3-trialkylsilyl(germyl)prop-2-yn-1-ols to propynals and the direct conversion of acetylenic alcohols to ynimines and enynes},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n06ABEH002008},
number = {6},
pages = {263--265},
doi = {10.1070/MC2005v015n06ABEH002008}
}
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Cite this
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Mareev, Alexander Vladimirovich, et al. “Microwave-assisted dry oxidation of 3-trialkylsilyl(germyl)prop-2-yn-1-ols to propynals and the direct conversion of acetylenic alcohols to ynimines and enynes.” Mendeleev Communications, vol. 15, no. 6, Nov. 2005, pp. 263-265. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n06ABEH002008.

Abstract

The efficient solvent-free microwave-assisted oxidation of 3-trialkylsilyl(germyl)prop-2-yn-1-ols with manganese dioxide or pyridinium chlorochromate to propynals and the direct conversion of acetylenic alcohols to the corresponding imines and Knövenagel adducts have been carried out.

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