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Thermodynamic characteristics of the resolvation of K+ and Cl– ions in mixtures of water with aprotic solvents

Vladimir Ivanovich Parfenyuk 1
Vladimir Ivanovich Parfenyuk
, 
Tatyana Ivanovna Chankina 1
Tatyana Ivanovna Chankina
10.1070/MC2005v015n05ABEH002140
Published 2005-09-09
Communication , Volume 15, Issue 5, 212-213
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Parfenyuk V. I., Chankina T. I. Thermodynamic characteristics of the resolvation of K+ and Cl– ions in mixtures of water with aprotic solvents // Mendeleev Communications. 2005. Vol. 15. No. 5. pp. 212-213.
GOST all authors (up to 50) Copy
Parfenyuk V. I., Chankina T. I. Thermodynamic characteristics of the resolvation of K+ and Cl– ions in mixtures of water with aprotic solvents // Mendeleev Communications. 2005. Vol. 15. No. 5. pp. 212-213.
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TY - JOUR
DO - 10.1070/MC2005v015n05ABEH002140
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n05ABEH002140
TI - Thermodynamic characteristics of the resolvation of K+ and Cl– ions in mixtures of water with aprotic solvents
T2 - Mendeleev Communications
AU - Parfenyuk, Vladimir Ivanovich
AU - Chankina, Tatyana Ivanovna
PY - 2005
DA - 2005/09/09
PB - Mendeleev Communications
SP - 212-213
IS - 5
VL - 15
ER -
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@article{2005_Parfenyuk,
author = {Vladimir Ivanovich Parfenyuk and Tatyana Ivanovna Chankina},
title = {Thermodynamic characteristics of the resolvation of K+ and Cl– ions in mixtures of water with aprotic solvents},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n05ABEH002140},
number = {5},
pages = {212--213},
doi = {10.1070/MC2005v015n05ABEH002140}
}
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Parfenyuk, Vladimir Ivanovich, and Tatyana Ivanovna Chankina. “Thermodynamic characteristics of the resolvation of K+ and Cl– ions in mixtures of water with aprotic solvents.” Mendeleev Communications, vol. 15, no. 5, Sep. 2005, pp. 212-213. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n05ABEH002140.

Abstract

The solvation of K+ and Cl– ions in water mixtures with aprotic solvents (acetone, acetonitrile, dimethylsulfoxide and dimethylformamide) was studied based on the analysis of primary effects of the medium of K+ and Cl– and the chemical Gibbs energies of transfer of these ions from water to the mixed solvents at 298.15 K obtained from Volta potential differences.

References

2.
The medium effect for single ionic species
Parsons R., Rubin B.T.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases, 1974
3.
The real free energies of solvation of ions in some non-aqueous and mixed solvents
Case B., Parsons R.
Transactions of the Faraday Society, 1967
7.
Recent aspects of single ion transfer properties
Gritzner G.
Pure and Applied Chemistry, 1988
8.
10.1070/MC2005v015n05ABEH002140_bib8
Lange
Z. Phys. Chem., 1930
10.
The concept and physical meaning of absolute electrode potential
Trasatti S.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1982
11.
10.1070/MC2005v015n05ABEH002140_bib11
Daghetti
Can. J. Chem., 1984
12.
Ionic hydration and the surface potential of aqueous electrolytes
Randles J.E.
Discussions of the Faraday Society, 1957
13.
The temperature-dependence of the surface potential of aqueous electrolytes
Randles J.E., Schiffrin D.J.
Journal of Electroanalytical Chemistry (1959), 1965
14.
Die Potentialsprünge zwischen Gasen und Flüssigkeiten
Kenrick F.B.
Zeitschrift fur Physikalische Chemie, 1896
15.
10.1070/MC2005v015n05ABEH002140_bib15
Bates
Determination of pH. Teory and Practice, 1964
16.
M M. Shul’ts, Uchen. Zap. Leningr. Gos. Univ., Ser. Khim. Nauk, 1953, 80 (in Russian).
17.
10.1070/MC2005v015n05ABEH002140_bib17
Parfenyuk
Kolloidn. Zh., 2002
18.
10.1070/MC2005v015n05ABEH002140_bib18
Parfenyuk
Kolloidn. Zh., 2004
19.
Activity coefficients of single ions (V) in acetone and acetone-water mixtures
Bax D., de Ligny C.L., Remijnse A.G.
Recueil des Travaux Chimiques des Pays-Bas, 1972
20.
Thermodynamic properties for transfer of electrolytes from water to acetonitrile and to acetonitrile + water mixtures
Cox B.G., Natarajan R., Waghorne W.E.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases, 1979