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Reaction of sodium diethylphosphite with Group VIB hexacarbonyls

Arcady Iskanderovich Kuramshin 1
Arcady Iskanderovich Kuramshin
, 
Andrey Aleksandrovich Nikolaev 1
Andrey Aleksandrovich Nikolaev
, 
Rafael Askhatovich Cherkasov 1
Rafael Askhatovich Cherkasov
10.1070/MC2005v015n05ABEH002133
Published 2005-09-09
Communication , Volume 15, Issue 5, 210-211
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Kuramshin A. I., Nikolaev A. A., Cherkasov R. A. Reaction of sodium diethylphosphite with Group VIB hexacarbonyls // Mendeleev Communications. 2005. Vol. 15. No. 5. pp. 210-211.
GOST all authors (up to 50) Copy
Kuramshin A. I., Nikolaev A. A., Cherkasov R. A. Reaction of sodium diethylphosphite with Group VIB hexacarbonyls // Mendeleev Communications. 2005. Vol. 15. No. 5. pp. 210-211.
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TY - JOUR
DO - 10.1070/MC2005v015n05ABEH002133
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n05ABEH002133
TI - Reaction of sodium diethylphosphite with Group VIB hexacarbonyls
T2 - Mendeleev Communications
AU - Kuramshin, Arcady Iskanderovich
AU - Nikolaev, Andrey Aleksandrovich
AU - Cherkasov, Rafael Askhatovich
PY - 2005
DA - 2005/09/09
PB - Mendeleev Communications
SP - 210-211
IS - 5
VL - 15
ER -
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@article{2005_Kuramshin,
author = {Arcady Iskanderovich Kuramshin and Andrey Aleksandrovich Nikolaev and Rafael Askhatovich Cherkasov},
title = {Reaction of sodium diethylphosphite with Group VIB hexacarbonyls},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n05ABEH002133},
number = {5},
pages = {210--211},
doi = {10.1070/MC2005v015n05ABEH002133}
}
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Kuramshin, Arcady Iskanderovich, et al. “Reaction of sodium diethylphosphite with Group VIB hexacarbonyls.” Mendeleev Communications, vol. 15, no. 5, Sep. 2005, pp. 210-211. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n05ABEH002133.

Abstract

The interaction of sodium diethylphosphite with the hexacarbonyl complexes of chromium-group metals occurs as a nucleophilic attack of the diethylphosphite anion at the carbon atom of the carbonyl groups as well as to the generation of the phosphaorganometallic species that are catalytically active in the phosphorylation of tetrachloroethylene.

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