Home / Publications / Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis

Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis

Nataliya Vital'evna Roznyatovskaya 1
Nataliya Vital'evna Roznyatovskaya
, 
Galina Aleksandrovna Tsirlina 1
Galina Aleksandrovna Tsirlina
, 
Vladimir V Roznyatovskii 1
Vladimir V Roznyatovskii
, 
Alexander Sergeyevich Mitiaev 1
Alexander Sergeyevich Mitiaev
, 
Yegor Dmitrievich Smurnyy 1
Yegor Dmitrievich Smurnyy
10.1070/MC2005v015n03ABEH002100
Published 2005-05-04
Communication , Volume 15, Issue 3, 93-95
3
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Roznyatovskaya N. V. et al. Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis // Mendeleev Communications. 2005. Vol. 15. No. 3. pp. 93-95.
GOST all authors (up to 50) Copy
Roznyatovskaya N. V., Tsirlina G. A., Roznyatovskii V. V., Mitiaev A. S., Smurnyy Y. D. Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis // Mendeleev Communications. 2005. Vol. 15. No. 3. pp. 93-95.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2005v015n03ABEH002100
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n03ABEH002100
TI - Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis
T2 - Mendeleev Communications
AU - Roznyatovskaya, Nataliya Vital'evna
AU - Tsirlina, Galina Aleksandrovna
AU - Roznyatovskii, Vladimir V
AU - Mitiaev, Alexander Sergeyevich
AU - Smurnyy, Yegor Dmitrievich
PY - 2005
DA - 2005/05/04
PB - Mendeleev Communications
SP - 93-95
IS - 3
VL - 15
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2005_Roznyatovskaya,
author = {Nataliya Vital'evna Roznyatovskaya and Galina Aleksandrovna Tsirlina and Vladimir V Roznyatovskii and Alexander Sergeyevich Mitiaev and Yegor Dmitrievich Smurnyy},
title = {Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n03ABEH002100},
number = {3},
pages = {93--95},
doi = {10.1070/MC2005v015n03ABEH002100}
}
MLA
Cite this
MLA Copy
Roznyatovskaya, Nataliya Vital'evna, et al. “Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis.” Mendeleev Communications, vol. 15, no. 3, May. 2005, pp. 93-95. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n03ABEH002100.

Abstract

The electrochemistry of the macrocyclic dicopper(II) and dinickel(II) complexes [M2L]Cl2, where L is the [2+2] condensation product of 1,3-diaminopropane and 2,6-diformyl-4-tert-butylphenol, is reported in relation to hydrogen peroxide electrocatalysis on mercury. The opposite effects observed with [Cu2L]Cl2 (inhibition) and [Ni2L]Cl2 (enhancement) are explained by different reduction mechanisms.

References

2.
The activation of small molecules by dinuclear complexes of copper and other metals
Vigato P.A., Tamburini S., Fenton D.E.
Coordination Chemistry Reviews, 1990
5.
Reaction between Various Copper(II) Complexes and Ascorbic Acid or 3,5-Di-t-butylcatechol
Oishi N., Nishida Y., Ida K., Kida S.
Bulletin of the Chemical Society of Japan, 1980
6.
ELECTROCHEMICAL REDUCTION OF OXYGEN
Bagotskii V.S., Nekrasov L.N., Shumilova N.A.
Russian Chemical Reviews, 1965
8.
Brdička R., Wiesner K.
Collection of Czechoslovak Chemical Communications, 2014
9.
10.1070/MC2005v015n03ABEH002100_bib9
Roznyatovskaya
Elektrokhimiya, 2004
10.
10.1070/MC2005v015n03ABEH002100_bib10
Pilkington
Aust. J. Chem., 1970
11.
N. V. Roznyatovskaya, S. Yu. Vassiliev, A. I. Yusipovich, G. A. Tsirlina and V. V. Roznyatovskii, J. Solid State Electrochem., in press. (Http://www.Springerlink.Com/Index/10.1007/S10008-004-0604-Z).
12.
10.1070/MC2005v015n03ABEH002100_bib12
Geyrovski
Osnovy polyarografii (Fundamentals of Polarography), 1965
14.
M. I. Borzenko, R. R. Nazmutdinov, D. V. Glukhov, G. A. Tsirlina and M. Probst, Chem. Phys., in press.
15.
10.1070/MC2005v015n03ABEH002100_bib15
Kryukova
Polyarograficheskii analiz (Polarographic Analysis), 1959