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Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes

Elena Nikolaevna Varaksina 1
Elena Nikolaevna Varaksina
,  , 
Alfia Akhmetovna Shtyrlina 1
Alfia Akhmetovna Shtyrlina
, 
Alexey Borisovich Dobrynin 1
Alexey Borisovich Dobrynin
, 
Igor Anatol'evich Litvinov 1
Igor Anatol'evich Litvinov
, 
Aleksandr Ivanovich Konovalov 1
Aleksandr Ivanovich Konovalov
10.1070/MC2005v015n03ABEH002069
Published 2005-05-04
Communication , Volume 15, Issue 3, 103-105
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Varaksina E. N. et al. Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes // Mendeleev Communications. 2005. Vol. 15. No. 3. pp. 103-105.
GOST all authors (up to 50) Copy
Varaksina E. N., Mironov V. F., Shtyrlina A. A., Dobrynin A. B., Litvinov I. A., Konovalov A. I. Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes // Mendeleev Communications. 2005. Vol. 15. No. 3. pp. 103-105.
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TY - JOUR
DO - 10.1070/MC2005v015n03ABEH002069
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n03ABEH002069
TI - Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes
T2 - Mendeleev Communications
AU - Varaksina, Elena Nikolaevna
AU - Mironov, Vladimir Fedorovich
AU - Shtyrlina, Alfia Akhmetovna
AU - Dobrynin, Alexey Borisovich
AU - Litvinov, Igor Anatol'evich
AU - Konovalov, Aleksandr Ivanovich
PY - 2005
DA - 2005/05/04
PB - Mendeleev Communications
SP - 103-105
IS - 3
VL - 15
ER -
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@article{2005_Varaksina,
author = {Elena Nikolaevna Varaksina and Vladimir Fedorovich Mironov and Alfia Akhmetovna Shtyrlina and Alexey Borisovich Dobrynin and Igor Anatol'evich Litvinov and Aleksandr Ivanovich Konovalov},
title = {Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n03ABEH002069},
number = {3},
pages = {103--105},
doi = {10.1070/MC2005v015n03ABEH002069}
}
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Varaksina, Elena Nikolaevna, et al. “Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes.” Mendeleev Communications, vol. 15, no. 3, May. 2005, pp. 103-105. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n03ABEH002069.

Abstract

The reactions of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes with molecular chlorine in an 1:1 ratio occur selectively to give 4-methyl-2,2,2,5-tetrachloro- and 5-methyl-2,2,2,6-tetrachlorobenzo[d]-1,3,2-dioxaphospholes, which undergo hydrolysis to 4-chloro-3-methyl- and 4-chloro-5-methyl-1,2-dihydroxybenzenes, respectively.

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