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The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand

,  , 
Sergey Zurabovich Vatsadze 1
Sergey Zurabovich Vatsadze
, 
Anna Anisimovna Moiseeva 1
Anna Anisimovna Moiseeva
, 
Fedor Sergeyevich Moiseev 1
Fedor Sergeyevich Moiseev
, 
Kim Petrovich Butin 1
Kim Petrovich Butin
, 
Nikolai Vasil'evich Zyk 1
Nikolai Vasil'evich Zyk
10.1070/MC2005v015n02ABEH002089
Published 2005-03-23
Communication , Volume 15, Issue 2, 48-50
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Majouga A. G. et al. The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand // Mendeleev Communications. 2005. Vol. 15. No. 2. pp. 48-50.
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Majouga A. G., Beloglazkina E. K., Vatsadze S. Z., Moiseeva A. A., Moiseev F. S., Butin K. P., Zyk N. V. The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand // Mendeleev Communications. 2005. Vol. 15. No. 2. pp. 48-50.
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TY - JOUR
DO - 10.1070/MC2005v015n02ABEH002089
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n02ABEH002089
TI - The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand
T2 - Mendeleev Communications
AU - Majouga, Alexander Georgievich
AU - Beloglazkina, Elena Kimovna
AU - Vatsadze, Sergey Zurabovich
AU - Moiseeva, Anna Anisimovna
AU - Moiseev, Fedor Sergeyevich
AU - Butin, Kim Petrovich
AU - Zyk, Nikolai Vasil'evich
PY - 2005
DA - 2005/03/23
PB - Mendeleev Communications
SP - 48-50
IS - 2
VL - 15
ER -
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@article{2005_Majouga,
author = {Alexander Georgievich Majouga and Elena Kimovna Beloglazkina and Sergey Zurabovich Vatsadze and Anna Anisimovna Moiseeva and Fedor Sergeyevich Moiseev and Kim Petrovich Butin and Nikolai Vasil'evich Zyk},
title = {The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n02ABEH002089},
number = {2},
pages = {48--50},
doi = {10.1070/MC2005v015n02ABEH002089}
}
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Majouga, Alexander Georgievich, et al. “The first example of a reversibly reducible CoII complex with an anionic 2-thiohydantoin-type ligand.” Mendeleev Communications, vol. 15, no. 2, Mar. 2005, pp. 48-50. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n02ABEH002089.

Abstract

The reaction of the potassium salt of 3-phenyl-5(Z)-(pyridin-2-ylmethylene)-2-thioxoimidazolidin-4-one (KL) with CoCl2·6H2O in MeCN results in formation of the neutral complex CoIIL2. According to single-crystal X-ray analysis, the CoII centre is coordinated to four nitrogen atoms of two organic ligands and has a distorted tetrahedral geometry. This complex undergoes electrochemical reduction with consequent two reversible and one quasi-reversible stages.

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