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4,5-Difluoro-1,2-dehydrobenzene: generation and cycloaddition reactions

, 
Svetlana Konstantinovna Kotovskaya 2
Svetlana Konstantinovna Kotovskaya
, 
Svetlana Aleksandrovna Romanova 2
Svetlana Aleksandrovna Romanova
, 
Oleg Nikolaevich Chupakhin 1
Oleg Nikolaevich Chupakhin
,  , 
Oleg Matveevich Nefedov 3
Oleg Matveevich Nefedov
10.1070/MC2005v015n02ABEH002072
Published 2005-03-23
Communication , Volume 15, Issue 2, 45-46
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Charushin V. N. et al. 4,5-Difluoro-1,2-dehydrobenzene: generation and cycloaddition reactions // Mendeleev Communications. 2005. Vol. 15. No. 2. pp. 45-46.
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Charushin V. N., Kotovskaya S. K., Romanova S. A., Chupakhin O. N., Tomilov Y. V., Nefedov O. M. 4,5-Difluoro-1,2-dehydrobenzene: generation and cycloaddition reactions // Mendeleev Communications. 2005. Vol. 15. No. 2. pp. 45-46.
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TY - JOUR
DO - 10.1070/MC2005v015n02ABEH002072
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n02ABEH002072
TI - 4,5-Difluoro-1,2-dehydrobenzene: generation and cycloaddition reactions
T2 - Mendeleev Communications
AU - Charushin, Valery Nikolaevich
AU - Kotovskaya, Svetlana Konstantinovna
AU - Romanova, Svetlana Aleksandrovna
AU - Chupakhin, Oleg Nikolaevich
AU - Tomilov, Yury Vasil'evich
AU - Nefedov, Oleg Matveevich
PY - 2005
DA - 2005/03/23
PB - Mendeleev Communications
SP - 45-46
IS - 2
VL - 15
ER -
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@article{2005_Charushin,
author = {Valery Nikolaevich Charushin and Svetlana Konstantinovna Kotovskaya and Svetlana Aleksandrovna Romanova and Oleg Nikolaevich Chupakhin and Yury Vasil'evich Tomilov and Oleg Matveevich Nefedov},
title = {4,5-Difluoro-1,2-dehydrobenzene: generation and cycloaddition reactions},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n02ABEH002072},
number = {2},
pages = {45--46},
doi = {10.1070/MC2005v015n02ABEH002072}
}
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Charushin, Valery Nikolaevich, et al. “4,5-Difluoro-1,2-dehydrobenzene: generation and cycloaddition reactions.” Mendeleev Communications, vol. 15, no. 2, Mar. 2005, pp. 45-46. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n02ABEH002072.

Abstract

The oxidation of 1-amino-5,6-difluorobenzotriazole with Pb(OAc)4 in dry CH2Cl2 afforded 4,5-difluoro-1,2-dehydrobenzene, a new active intermediate, which can be used in situ for the synthesis of fluorinated carbo- and heterocyclic compounds via cycloaddition reactions.

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