Home / Publications / Reaction of α-methylstyrene with arylsulfonyl chlorides: spontaneous dehydrochlorination against the Zaitsev rule

Reaction of α-methylstyrene with arylsulfonyl chlorides: spontaneous dehydrochlorination against the Zaitsev rule

Valentina Vladimirovna Ermolaeva 1
Valentina Vladimirovna Ermolaeva
, 
Nina Petrovna Gerasimova 1
Nina Petrovna Gerasimova
, 
Nikolai Alekseevich Nozhnin 1
Nikolai Alekseevich Nozhnin
, 
Yuri Aleksandrovich Moskvichev 1
Yuri Aleksandrovich Moskvichev
, 
Evgeni Mikhaylovich Alov 1
Evgeni Mikhaylovich Alov
, 
Angelina Sergeevna Danilova 1
Angelina Sergeevna Danilova
, 
Irina V Shutova 1
Irina V Shutova
, 
Olga S Kozlova 1
Olga S Kozlova
10.1070/MC2005v015n02ABEH001930
Published 2005-03-23
Communication , Volume 15, Issue 2, 84-86
4
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Ermolaeva V. V. et al. Reaction of α-methylstyrene with arylsulfonyl chlorides: spontaneous dehydrochlorination against the Zaitsev rule // Mendeleev Communications. 2005. Vol. 15. No. 2. pp. 84-86.
GOST all authors (up to 50) Copy
Ermolaeva V. V., Gerasimova N. P., Nozhnin N. A., Moskvichev Y. A., Alov E. M., Danilova A. S., Shutova I. V., Kozlova O. S. Reaction of α-methylstyrene with arylsulfonyl chlorides: spontaneous dehydrochlorination against the Zaitsev rule // Mendeleev Communications. 2005. Vol. 15. No. 2. pp. 84-86.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2005v015n02ABEH001930
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n02ABEH001930
TI - Reaction of α-methylstyrene with arylsulfonyl chlorides: spontaneous dehydrochlorination against the Zaitsev rule
T2 - Mendeleev Communications
AU - Ermolaeva, Valentina Vladimirovna
AU - Gerasimova, Nina Petrovna
AU - Nozhnin, Nikolai Alekseevich
AU - Moskvichev, Yuri Aleksandrovich
AU - Alov, Evgeni Mikhaylovich
AU - Danilova, Angelina Sergeevna
AU - Shutova, Irina V
AU - Kozlova, Olga S
PY - 2005
DA - 2005/03/23
PB - Mendeleev Communications
SP - 84-86
IS - 2
VL - 15
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2005_Ermolaeva,
author = {Valentina Vladimirovna Ermolaeva and Nina Petrovna Gerasimova and Nikolai Alekseevich Nozhnin and Yuri Aleksandrovich Moskvichev and Evgeni Mikhaylovich Alov and Angelina Sergeevna Danilova and Irina V Shutova and Olga S Kozlova},
title = {Reaction of α-methylstyrene with arylsulfonyl chlorides: spontaneous dehydrochlorination against the Zaitsev rule},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n02ABEH001930},
number = {2},
pages = {84--86},
doi = {10.1070/MC2005v015n02ABEH001930}
}
MLA
Cite this
MLA Copy
Ermolaeva, Valentina Vladimirovna, et al. “Reaction of α-methylstyrene with arylsulfonyl chlorides: spontaneous dehydrochlorination against the Zaitsev rule.” Mendeleev Communications, vol. 15, no. 2, Mar. 2005, pp. 84-86. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n02ABEH001930.

Abstract

The free-radical addition of arylsulfonyl chlorides to α-methylstyrene in the presence of copper chloride is accompanied by the dehydrochlorination of the adducts formed.

References

2.
The Copper-Catalyzed Addition of Arenesulfonyl Chlorides to Conjugated Dienes, Trienes, and Phenylacetylene
Truce W., Goralski C., Christensen L., Bavry R.
Journal of Organic Chemistry, 1970
4.
Redox transfer. Part VIII. Addition of benzenesulphonyl chloride and carbon tetrachloride to substituted styrenes: a kinetic study
Or(Orochov) A., Asscher M., Vofsi D.
Journal of the Chemical Society Perkin Transactions 2, 1973
5.
Convenient Methods for the Preparation of Vinylic and Allylic Sulfones from Alkenes, Haloalkanes, and Aldehydes. Stereochemistry of the Conversion of Vinylic Sulfones to the Corresponding Allylic Sulfones
Inomata K., Sasaoka S., Kobayashi T., Tanaka Y., Igarashi S., Ohtani T., Kinoshita H., Kotake H.
Bulletin of the Chemical Society of Japan, 1987
6.
Copper-catalyzed additions of sulfonyl iodides to simple and cyclic alkenes
Liu L.K., Chi Y., Jen K.
Journal of Organic Chemistry, 1980
8.
10.1070/MC2005v015n02ABEH001930_bib8
Konyushkin
Izv. Akad. Nauk SSSR, Ser. Khim., 1977
10.
Addition of sulfonyl iodides to allenes
Truce W.E., Heuring D.L., Wolf G.C.
Journal of Organic Chemistry, 1974
12.
Heats of Hydrogenation. VI. Heats of Hydrogenation of Some Substituted Ethylenes1
Turner R.B., Nettleton D.E., Perelman M.
Journal of the American Chemical Society, 1958