Home / Publications / Characterization of low-spin ferric hydroperoxo complexes with N,N’-dimethyl-N,N’-bis(2-pyridylmethyl)-1,2-diaminoethane

Characterization of low-spin ferric hydroperoxo complexes with N,N’-dimethyl-N,N’-bis(2-pyridylmethyl)-1,2-diaminoethane

Eduard Anatol'evich Duban 1
Eduard Anatol'evich Duban
, 
Konstantin Petrovich Bryliakov 1
Konstantin Petrovich Bryliakov
, 
Evgenii Pavlovich Talsi 1
Evgenii Pavlovich Talsi
10.1070/MC2005v015n01ABEH001981
Published 2005-02-09
Communication , Volume 15, Issue 1, 12-14
14
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Duban E. A., Bryliakov K. P., Talsi E. P. Characterization of low-spin ferric hydroperoxo complexes with N,N’-dimethyl-N,N’-bis(2-pyridylmethyl)-1,2-diaminoethane // Mendeleev Communications. 2005. Vol. 15. No. 1. pp. 12-14.
GOST all authors (up to 50) Copy
Duban E. A., Bryliakov K. P., Talsi E. P. Characterization of low-spin ferric hydroperoxo complexes with N,N’-dimethyl-N,N’-bis(2-pyridylmethyl)-1,2-diaminoethane // Mendeleev Communications. 2005. Vol. 15. No. 1. pp. 12-14.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2005v015n01ABEH001981
UR - https://mendcomm.colab.ws/publications/10.1070/MC2005v015n01ABEH001981
TI - Characterization of low-spin ferric hydroperoxo complexes with N,N’-dimethyl-N,N’-bis(2-pyridylmethyl)-1,2-diaminoethane
T2 - Mendeleev Communications
AU - Duban, Eduard Anatol'evich
AU - Bryliakov, Konstantin Petrovich
AU - Talsi, Evgenii Pavlovich
PY - 2005
DA - 2005/02/09
PB - Mendeleev Communications
SP - 12-14
IS - 1
VL - 15
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2005_Duban,
author = {Eduard Anatol'evich Duban and Konstantin Petrovich Bryliakov and Evgenii Pavlovich Talsi},
title = {Characterization of low-spin ferric hydroperoxo complexes with N,N’-dimethyl-N,N’-bis(2-pyridylmethyl)-1,2-diaminoethane},
journal = {Mendeleev Communications},
year = {2005},
volume = {15},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2005v015n01ABEH001981},
number = {1},
pages = {12--14},
doi = {10.1070/MC2005v015n01ABEH001981}
}
MLA
Cite this
MLA Copy
Duban, Eduard Anatol'evich, et al. “Characterization of low-spin ferric hydroperoxo complexes with N,N’-dimethyl-N,N’-bis(2-pyridylmethyl)-1,2-diaminoethane.” Mendeleev Communications, vol. 15, no. 1, Feb. 2005, pp. 12-14. https://mendcomm.colab.ws/publications/10.1070/MC2005v015n01ABEH001981.

Abstract

Hydroperoxo intermediates formed by the interaction of [FeII(BPMEN)(MeCN)2](ClO4)2 [BPMEN = N,N’-dimethyl-N,N’-bis-(2-pyridylmethyl)-1,2-diaminoethane] with H2O2 in a CH2Cl2–MeCN mixture were characterised using EPR spectroscopy.

References

2.
A Synthetically Useful, Self-Assembling MMO Mimic System for Catalytic Alkene Epoxidation with Aqueous H2O2
White M.C., Doyle A.G., Jacobsen E.N.
Journal of the American Chemical Society, 2001
3.
Olefin Cis-Dihydroxylation versus Epoxidation by Non-Heme Iron Catalysts:  Two Faces of an FeIII−OOH Coin
Chen K., Costas M., Kim J., Tipton A.K., Que L.
Journal of the American Chemical Society, 2002
4.
Lobanova M.V., Bryliakov K.P., Duban E.A., Talsi E.P.
Mendeleev Communications, 2003
6.
10.1070/MC2005v015n01ABEH001981_bib6
Fontecave
Chem. Rev., 1998
7.
10.1070/MC2005v015n01ABEH001981_bib7
Costas
Chem. Rev., 2000
10.
Solid and solution state structures of mono- and di-nuclear iron(III) complexes of related hexadentate and pentadentate aminopyridyl ligands
Duelund L., Hazell R., McKenzie C.J., Preuss Nielsen L., Toftlund H.
Journal of the Chemical Society Dalton Transactions, 2001
11.
Mononuclear Fe(II) and Fe(III) complexes with the tetradentate ligand N,N′-bisbenzyl-N,N′-bis(2-pyridylmethyl)-ethane-1,2-diamine. Synthesis and characterisation
Simaan J., Poussereau S., Blondin G., Girerd J., Defaye D., Philouze C., Guilhem J., Tchertanov L.
Inorganica Chimica Acta, 2000
13.
Sulfide Oxidation by Hydrogen Peroxide Catalyzed by Iron Complexes: Two Metal Centers Are Better Than One
Mekmouche Y., Hummel H., Ho R.Y., Que, Jr. L., Schünemann V., Thomas F., Trautwein A.X., Lebrun C., Gorgy K., Leprêtre J., Collomb M., Deronzier A., Fontecave M., Ménage S., et. al.
Chemistry - A European Journal, 2002