Home / Publications / Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines

Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines

Katsubiro Maeda 1
Katsubiro Maeda
, 
Kazuhiro Hatanaka 1
Kazuhiro Hatanaka
, 
Eiji Yashima 1
Eiji Yashima
10.1070/MC2004v014n06ABEH002074
Published 2004-12-17
Communication , Volume 14, Issue 6, 231-233
8
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Maeda K., Hatanaka K., Yashima E. Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 231-233.
GOST all authors (up to 50) Copy
Maeda K., Hatanaka K., Yashima E. Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 231-233.
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TY - JOUR
DO - 10.1070/MC2004v014n06ABEH002074
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002074
TI - Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines
T2 - Mendeleev Communications
AU - Maeda, Katsubiro
AU - Hatanaka, Kazuhiro
AU - Yashima, Eiji
PY - 2004
DA - 2004/12/17
PB - Mendeleev Communications
SP - 231-233
IS - 6
VL - 14
ER -
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@article{2004_Maeda,
author = {Katsubiro Maeda and Kazuhiro Hatanaka and Eiji Yashima},
title = {Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002074},
number = {6},
pages = {231--233},
doi = {10.1070/MC2004v014n06ABEH002074}
}
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Maeda, Katsubiro, et al. “Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines.” Mendeleev Communications, vol. 14, no. 6, Dec. 2004, pp. 231-233. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002074.

Abstract

An optically inactive cis-transoidal poly[(4-carboxyphenyl)acetylene] was found to form a predominantly one-handed helical conformation upon complexation with optically active amines and amino alcohols in the solid state, resulting in a characteristic induced circular dichroism in the polymer backbone region.

References

2.
Solvent-Free Organic Synthesis
Tanaka K., Toda F.
Chemical Reviews, 2000
6.
Solid-State Supramolecular Chirogenesis: High Optical Activity and Gradual Development of Zinc Octaethylporphyrin Aggregates
Borovkov V.V., Harada T., Hembury G.A., Inoue Y., Kuroda R.
Angewandte Chemie - International Edition, 2003
7.
Poly((4-carboxyphenyl)acetylene) as a Probe for Chirality Assignment of Amines by Circular Dichroism
Yashima E., Matsushima T., Okamoto Y.
Journal of the American Chemical Society, 1995
14.
A Helical Polyelectrolyte Induced by Specific Interactions with Biomolecules in Water
Onouchi H., Maeda K., Yashima E.
Journal of the American Chemical Society, 2001
17.
A solid-state dedicated circular dichroism spectrophotometer: Development and application
Kuroda R., Harada T., Shindo Y.
Review of Scientific Instruments, 2001
18.
Pressure-Induced Cis to Trans Isomerization of Poly(o-methoxyphenylacetylene) Polymerized by Rh Complex Catalyst. A Raman, X-ray, and ESR Study
Tabata M., Takamura H., Yokota K., Nozaki Y., Hoshina T., Minakawa H., Kodaira K.
Macromolecules, 1994
20.
Influence of water on the chirality of camphorsulfonic acid-doped polyaniline
Egan V., Bernstein R., Hohmann L., Tran T., Kaner R.B.
Chemical Communications, 2001
21.
Understanding Solid/Solid Organic Reactions
Rothenberg G., Downie A.P., Raston C.L., Scott J.L.
Journal of the American Chemical Society, 2001
23.
Controlled Incorporation of Water Molecules into Carboxy Hydrogen-Bond Networks:  A Designed Approach
Pérez C., Rodríguez M.L., Foces-Foces C., Pérez-Hernández N., Pérez R., Martín J.D.
Organic Letters, 2003
25.
Detection and Amplification of Chirality by Helical Polymers
Yashima E., Maeda K., Nishimura T.
Chemistry - A European Journal, 2004