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Resolution and racemization of nonbenzenoid atropenantiomers

Pavel V Novikov 1
Pavel V Novikov
, 
Oleg Robertovich Malyshev 2
Oleg Robertovich Malyshev
, 
Konstantin Alexandrovich Lyssenko 3
Konstantin Alexandrovich Lyssenko
, 
Remir Grigorevich Kostyanovsky 1
Remir Grigorevich Kostyanovsky
10.1070/MC2004v014n06ABEH002049
Published 2004-12-17
Communication , Volume 14, Issue 6, 310-312
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Novikov P. V. et al. Resolution and racemization of nonbenzenoid atropenantiomers // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 310-312.
GOST all authors (up to 50) Copy
Novikov P. V., Malyshev O. R., Lyssenko K. A., Kostyanovsky R. G. Resolution and racemization of nonbenzenoid atropenantiomers // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 310-312.
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TY - JOUR
DO - 10.1070/MC2004v014n06ABEH002049
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002049
TI - Resolution and racemization of nonbenzenoid atropenantiomers
T2 - Mendeleev Communications
AU - Novikov, Pavel V
AU - Malyshev, Oleg Robertovich
AU - Lyssenko, Konstantin Alexandrovich
AU - Kostyanovsky, Remir Grigorevich
PY - 2004
DA - 2004/12/17
PB - Mendeleev Communications
SP - 310-312
IS - 6
VL - 14
ER -
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@article{2004_Novikov,
author = {Pavel V Novikov and Oleg Robertovich Malyshev and Konstantin Alexandrovich Lyssenko and Remir Grigorevich Kostyanovsky},
title = {Resolution and racemization of nonbenzenoid atropenantiomers},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002049},
number = {6},
pages = {310--312},
doi = {10.1070/MC2004v014n06ABEH002049}
}
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Novikov, Pavel V., et al. “Resolution and racemization of nonbenzenoid atropenantiomers.” Mendeleev Communications, vol. 14, no. 6, Dec. 2004, pp. 310-312. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002049.

Abstract

The three-step synthesis of adduct 3 has been reinvestigated; enantiomers 3a and 3b have been separated by enantioselective chromatography and the racemization barrier of 3a was determined as ΔG≠ = 24.4 kcal mol−1 (16 °C).

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