Home / Publications / Is the unexpected behaviour of the resolved K3[CrIII(C2O4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnIICrIII(C2O4)3 NEt(n-Pr)(n-Bu)(n-C5H11)] network?

Is the unexpected behaviour of the resolved K3[CrIII(C2O4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnIICrIII(C2O4)3 NEt(n-Pr)(n-Bu)(n-C5H11)] network?

Michel Gruselle 1
Michel Gruselle
, 
Cyrille Train 1
Cyrille Train
, 
Nikolai Sarkisovich Ovanesyan 2
Nikolai Sarkisovich Ovanesyan
, 
Viktor Dmitrievich Makhaev 2
Viktor Dmitrievich Makhaev
, 
Christine Cordier 3
Christine Cordier
10.1070/MC2004v014n06ABEH002035
Published 2004-12-17
Communication , Volume 14, Issue 6, 284-285
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Gruselle M. et al. Is the unexpected behaviour of the resolved K3[CrIII(C2O4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnIICrIII(C2O4)3 NEt(n-Pr)(n-Bu)(n-C5H11)] network? // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 284-285.
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Gruselle M., Train C., Ovanesyan N. S., Makhaev V. D., Cordier C. Is the unexpected behaviour of the resolved K3[CrIII(C2O4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnIICrIII(C2O4)3 NEt(n-Pr)(n-Bu)(n-C5H11)] network? // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 284-285.
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TY - JOUR
DO - 10.1070/MC2004v014n06ABEH002035
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002035
TI - Is the unexpected behaviour of the resolved K3[CrIII(C2O4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnIICrIII(C2O4)3 NEt(n-Pr)(n-Bu)(n-C5H11)] network?
T2 - Mendeleev Communications
AU - Gruselle, Michel
AU - Train, Cyrille
AU - Ovanesyan, Nikolai Sarkisovich
AU - Makhaev, Viktor Dmitrievich
AU - Cordier, Christine
PY - 2004
DA - 2004/12/17
PB - Mendeleev Communications
SP - 284-285
IS - 6
VL - 14
ER -
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@article{2004_Gruselle,
author = {Michel Gruselle and Cyrille Train and Nikolai Sarkisovich Ovanesyan and Viktor Dmitrievich Makhaev and Christine Cordier},
title = {Is the unexpected behaviour of the resolved K3[CrIII(C2O4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnIICrIII(C2O4)3 NEt(n-Pr)(n-Bu)(n-C5H11)] network?},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002035},
number = {6},
pages = {284--285},
doi = {10.1070/MC2004v014n06ABEH002035}
}
MLA
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Gruselle, Michel, et al. “Is the unexpected behaviour of the resolved K3[CrIII(C2O4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnIICrIII(C2O4)3 NEt(n-Pr)(n-Bu)(n-C5H11)] network?.” Mendeleev Communications, vol. 14, no. 6, Dec. 2004, pp. 284-285. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002035.

Abstract

Racemic and resolved [CrIII(C2O4)3]K3 dissolved in water were investigated by IR spectroscopy. Compared to the racemic compound, the spectrum of the resolved one exhibits additional peaks, which have a complex temporal evolution. These peaks are attributed to water molecules coordinated to the metal ion and tentatively related to the formation of a pure chiral solid phase of two-dimensional (2D) oxalate-based Mn–Cr networks starting from partially resolved CrIII(C2O4)3]3−.

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