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Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion

Michel Gruselle 1
Michel Gruselle
, 
René Thouvenot 1
René Thouvenot
, 
Régis Caspar 1
Régis Caspar
, 
Kamal Boubekeur 1
Kamal Boubekeur
, 
Hani Amouri 1
Hani Amouri
, 
Mikhail Aleksandrovich Ivanov 2
Mikhail Aleksandrovich Ivanov
, 
Kaia Tõnsuaadu 3
Kaia Tõnsuaadu
10.1070/MC2004v014n06ABEH002034
Published 2004-12-17
Communication , Volume 14, Issue 6, 282-283
15
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Gruselle M. et al. Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 282-283.
GOST all authors (up to 50) Copy
Gruselle M., Thouvenot R., Caspar R., Boubekeur K., Amouri H., Ivanov M. A., Tõnsuaadu K. Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 282-283.
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TY - JOUR
DO - 10.1070/MC2004v014n06ABEH002034
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002034
TI - Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion
T2 - Mendeleev Communications
AU - Gruselle, Michel
AU - Thouvenot, René
AU - Caspar, Régis
AU - Boubekeur, Kamal
AU - Amouri, Hani
AU - Ivanov, Mikhail Aleksandrovich
AU - Tõnsuaadu, Kaia
PY - 2004
DA - 2004/12/17
PB - Mendeleev Communications
SP - 282-283
IS - 6
VL - 14
ER -
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@article{2004_Gruselle,
author = {Michel Gruselle and René Thouvenot and Régis Caspar and Kamal Boubekeur and Hani Amouri and Mikhail Aleksandrovich Ivanov and Kaia Tõnsuaadu},
title = {Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002034},
number = {6},
pages = {282--283},
doi = {10.1070/MC2004v014n06ABEH002034}
}
MLA
Cite this
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Gruselle, Michel, et al. “Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion.” Mendeleev Communications, vol. 14, no. 6, Dec. 2004, pp. 282-283. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002034.

Abstract

The synthesis of cis-Ru(phen)2(MeCN)2][(Δ)-tris(tetrachlorobenzenediolato)phosphate(V)]2 abbreviated as [1]-[Δ-TRISPHAT]2 and the separation of a mixture of the diastereomeric ion pairs by column chromatography are considered. The X-ray structure of [Δ-1][Δ-TRISPHAT]2 is briefly described, as well as the CD curves of [Δ-1][Δ-TRISPHAT]2 and [Δ-1][Δ-TRISPHAT]2 fractions.

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