Home / Publications / An enantiomerically pure dinuclear triple-stranded helicate: X-ray structure, CD spectroscopy and DFT calculations

An enantiomerically pure dinuclear triple-stranded helicate: X-ray structure, CD spectroscopy and DFT calculations

Markus Albrecht 1
Markus Albrecht
Ingo Janser 1
Ingo Janser
Jörg Fleischhauer 1
Jörg Fleischhauer
Yuekui Wang 1
Yuekui Wang
Gerhard Raabe 1
Gerhard Raabe
Roland Fröhlich 2
Roland Fröhlich
Published 2004-12-17
CommunicationVolume 14, Issue 6, 250-253
29
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Albrecht M. et al. An enantiomerically pure dinuclear triple-stranded helicate: X-ray structure, CD spectroscopy and DFT calculations // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 250-253.
GOST all authors (up to 50) Copy
Albrecht M., Janser I., Fleischhauer J., Wang Y., Raabe G., Fröhlich R. An enantiomerically pure dinuclear triple-stranded helicate: X-ray structure, CD spectroscopy and DFT calculations // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 250-253.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2004v014n06ABEH002031
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002031
TI - An enantiomerically pure dinuclear triple-stranded helicate: X-ray structure, CD spectroscopy and DFT calculations
T2 - Mendeleev Communications
AU - Albrecht, Markus
AU - Janser, Ingo
AU - Fleischhauer, Jörg
AU - Wang, Yuekui
AU - Raabe, Gerhard
AU - Fröhlich, Roland
PY - 2004
DA - 2004/12/17
PB - Mendeleev Communications
SP - 250-253
IS - 6
VL - 14
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2004_Albrecht,
author = {Markus Albrecht and Ingo Janser and Jörg Fleischhauer and Yuekui Wang and Gerhard Raabe and Roland Fröhlich},
title = {An enantiomerically pure dinuclear triple-stranded helicate: X-ray structure, CD spectroscopy and DFT calculations},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002031},
number = {6},
pages = {250--253},
doi = {10.1070/MC2004v014n06ABEH002031}
}
MLA
Cite this
MLA Copy
Albrecht, Markus, et al. “An enantiomerically pure dinuclear triple-stranded helicate: X-ray structure, CD spectroscopy and DFT calculations.” Mendeleev Communications, vol. 14, no. 6, Dec. 2004, pp. 250-253. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002031.

Abstract

An enantiomerically pure dinuclear triple-stranded titanium(IV) helicate is formed from a dicatechol diimine ligand with an (R,R)-1,2-diaminocyclohexane spacer and its stereochemical features are elucidated by experimental and theoretical methods.

References

1.
10.1070/MC2004v014n06ABEH002031_bib1
van’t Hoff
Arch. Neerl. Sci. Exactes Nat., 1874
2.
10.1070/MC2004v014n06ABEH002031_bib2
LeBel
Bull. Soc. Chim. Fr., 1874
3.
Beitrag zur Konstitution anorganischer Verbindungen
Werner A.
Zeitschrift fur Anorganische und Allgemeine Chemie, 1893
4.
10.1070/MC2004v014n06ABEH002031_bib4
von Zelewsky
Stereochemistry of Coordination Compounds, 1996
8.
Imposition of Chirality in a Dinuclear Triple-Stranded Helicate by Ion Pair Formation1
Yeh R.M., Ziegler M., Johnson D.W., Terpin A.J., Raymond K.N.
Inorganic Chemistry, 2001
10.
Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand
Albrecht M., Schmid S., deGroot M., Weis P., Fröhlich R.
Chemical Communications, 2003
12.
Dicatechol-diimines: easily accessible ligands for the self-assembly of dinuclear triple-stranded helicates
Albrecht M., Janser I., Kamptmann S., Weis P., Wibbeling B., Fröhlich R.
Dalton Transactions, 2004
17.
Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr
18.
10.1070/MC2004v014n06ABEH002031_bib15
Ahlrichs
1998
19.
Circular dichroism and optical rotation
Schellman J.A.
Chemical Reviews, 1975
20.
R. Woody, private communication.
21.
Determination of the absolute configuration of calliactine by quantum chemical calculations
Voloshina E., Raabe G., Estermeier M., Steffan B., Fleischhauer J.
International Journal of Quantum Chemistry, 2004