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The photochemistry of optically active (E)-cyclooctene: lamp versus laser

Fang Gao 1
Fang Gao
, 
Run-hua Li 2
Run-hua Li
, 
Robert N Compton 1, 2
Robert N Compton
, 
Richard M Pagni 1
Richard M Pagni
10.1070/MC2004v014n06ABEH002012
Published 2004-12-17
Communication , Volume 14, Issue 6, 297-299
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Gao F. et al. The photochemistry of optically active (E)-cyclooctene: lamp versus laser // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 297-299.
GOST all authors (up to 50) Copy
Gao F., Li R., Compton R. N., Pagni R. M. The photochemistry of optically active (E)-cyclooctene: lamp versus laser // Mendeleev Communications. 2004. Vol. 14. No. 6. pp. 297-299.
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TY - JOUR
DO - 10.1070/MC2004v014n06ABEH002012
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002012
TI - The photochemistry of optically active (E)-cyclooctene: lamp versus laser
T2 - Mendeleev Communications
AU - Gao, Fang
AU - Li, Run-hua
AU - Compton, Robert N
AU - Pagni, Richard M
PY - 2004
DA - 2004/12/17
PB - Mendeleev Communications
SP - 297-299
IS - 6
VL - 14
ER -
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@article{2004_Gao,
author = {Fang Gao and Run-hua Li and Robert N Compton and Richard M Pagni},
title = {The photochemistry of optically active (E)-cyclooctene: lamp versus laser},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002012},
number = {6},
pages = {297--299},
doi = {10.1070/MC2004v014n06ABEH002012}
}
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Gao, Fang, et al. “The photochemistry of optically active (E)-cyclooctene: lamp versus laser.” Mendeleev Communications, vol. 14, no. 6, Dec. 2004, pp. 297-299. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n06ABEH002012.

Abstract

The photochemistry of optically active (E)-cyclooctene in cyclopentane was initiated with a lamp at ca. 254 nm and a Nd-YAG laser at 266 nm. The alkene racemizes slightly faster than it isomerizes to (Z)-cyclooctene, suggesting a previously hidden mechanism of E–Z photointerconversion. The photoreaction at 266 nm may be multiphoton in character.

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