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Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran

Konstantin Alexandrovich Lyssenko 1
Konstantin Alexandrovich Lyssenko
, 
Vladimir Aleksandrovich Ponomarev 2
Vladimir Aleksandrovich Ponomarev
, 
Mikhail Evguen'evich Gurskii 2
Mikhail Evguen'evich Gurskii
, 
Yurii Nikolaevich Bubnov 1
Yurii Nikolaevich Bubnov
, 
Mikhail Yuvenal'evich Antipin 1
Mikhail Yuvenal'evich Antipin
10.1070/MC2004v014n05ABEH001920
Published 2004-09-29
Communication , Volume 14, Issue 5, 189-191
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Lyssenko K. A. et al. Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran // Mendeleev Communications. 2004. Vol. 14. No. 5. pp. 189-191.
GOST all authors (up to 50) Copy
Lyssenko K. A., Ponomarev V. A., Gurskii M. E., Bubnov Y. N., Antipin M. Y. Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran // Mendeleev Communications. 2004. Vol. 14. No. 5. pp. 189-191.
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TY - JOUR
DO - 10.1070/MC2004v014n05ABEH001920
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n05ABEH001920
TI - Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran
T2 - Mendeleev Communications
AU - Lyssenko, Konstantin Alexandrovich
AU - Ponomarev, Vladimir Aleksandrovich
AU - Gurskii, Mikhail Evguen'evich
AU - Bubnov, Yurii Nikolaevich
AU - Antipin, Mikhail Yuvenal'evich
PY - 2004
DA - 2004/09/29
PB - Mendeleev Communications
SP - 189-191
IS - 5
VL - 14
ER -
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@article{2004_Lyssenko,
author = {Konstantin Alexandrovich Lyssenko and Vladimir Aleksandrovich Ponomarev and Mikhail Evguen'evich Gurskii and Yurii Nikolaevich Bubnov and Mikhail Yuvenal'evich Antipin},
title = {Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n05ABEH001920},
number = {5},
pages = {189--191},
doi = {10.1070/MC2004v014n05ABEH001920}
}
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Lyssenko, Konstantin Alexandrovich, et al. “Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran.” Mendeleev Communications, vol. 14, no. 5, Sep. 2004, pp. 189-191. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n05ABEH001920.

Abstract

The X-ray diffraction studies and B3LYP/6-311G* calculations of the complexes of 1-boraadamantane and 4-bromo-1-boraadamantane with THF have revealed that the introduction of a halogen atom results in a shortening of the B−O bond due to intramolecular polarization.

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