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Synthesis of 2-aryl-4,6-dinitrobenzo[d]isothiazolium from 2,4,6-trinitrotoluene

Oleg Yuryevich Sapozhnikov 1
Oleg Yuryevich Sapozhnikov
, 
Vasily Victorovich Mezhnev 1
Vasily Victorovich Mezhnev
, 
Elena V Smirnova 1
Elena V Smirnova
, 
Boris Grigor'evich Kimel 1
Boris Grigor'evich Kimel
, 
Mikhail Dmitrievich Dutov 1
Mikhail Dmitrievich Dutov
, 
Svyatoslav Arkad'evich Shevelev 1
Svyatoslav Arkad'evich Shevelev
10.1070/MC2004v014n05ABEH001913
Published 2004-09-29
Communication , Volume 14, Issue 5, 207-208
4
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Sapozhnikov O. Y. et al. Synthesis of 2-aryl-4,6-dinitrobenzo[d]isothiazolium from 2,4,6-trinitrotoluene // Mendeleev Communications. 2004. Vol. 14. No. 5. pp. 207-208.
GOST all authors (up to 50) Copy
Sapozhnikov O. Y., Mezhnev V. V., Smirnova E. V., Kimel B. G., Dutov M. D., Shevelev S. A. Synthesis of 2-aryl-4,6-dinitrobenzo[d]isothiazolium from 2,4,6-trinitrotoluene // Mendeleev Communications. 2004. Vol. 14. No. 5. pp. 207-208.
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TY - JOUR
DO - 10.1070/MC2004v014n05ABEH001913
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n05ABEH001913
TI - Synthesis of 2-aryl-4,6-dinitrobenzo[d]isothiazolium from 2,4,6-trinitrotoluene
T2 - Mendeleev Communications
AU - Sapozhnikov, Oleg Yuryevich
AU - Mezhnev, Vasily Victorovich
AU - Smirnova, Elena V
AU - Kimel, Boris Grigor'evich
AU - Dutov, Mikhail Dmitrievich
AU - Shevelev, Svyatoslav Arkad'evich
PY - 2004
DA - 2004/09/29
PB - Mendeleev Communications
SP - 207-208
IS - 5
VL - 14
ER -
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@article{2004_Sapozhnikov,
author = {Oleg Yuryevich Sapozhnikov and Vasily Victorovich Mezhnev and Elena V Smirnova and Boris Grigor'evich Kimel and Mikhail Dmitrievich Dutov and Svyatoslav Arkad'evich Shevelev},
title = {Synthesis of 2-aryl-4,6-dinitrobenzo[d]isothiazolium from 2,4,6-trinitrotoluene},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n05ABEH001913},
number = {5},
pages = {207--208},
doi = {10.1070/MC2004v014n05ABEH001913}
}
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Sapozhnikov, Oleg Yuryevich, et al. “Synthesis of 2-aryl-4,6-dinitrobenzo[d]isothiazolium from 2,4,6-trinitrotoluene.” Mendeleev Communications, vol. 14, no. 5, Sep. 2004, pp. 207-208. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n05ABEH001913.

Abstract

A method for the synthesis of previously unknown 2-aryl-4,6-dinitrobenzo[d]isothiazolium has been developed based on the replacement of ortho-NO2 in N-(2,4,6-trinitrobenzylidene)anilines by treatment with PhCH2SH/K2CO3 followed by conversion of the resulting N-(2-benzylthio-4,6-dinitrobenzylidene)anilines with SO2C12.

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