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Synthesis and crystal structure of trinuclear carboxylate complexes M₃(μ₃-O)(CF₃COO)₆L₃

Tatyana Yur'evna Glazunova ¹

Tatyana Yur'evna Glazunova

Alexander Ivanovich Boltalin ¹

Alexander Ivanovich Boltalin

Sergey Igorevich Troyanov ¹

Sergey Igorevich Troyanov

0000-0003-1663-0341

¹ Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

10.1070/MC2004v014n04ABEH001953

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Published 2004-09-07

Communication , Volume 14, Issue 4, 141-143

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Glazunova T. Y., Boltalin A. I., Troyanov S. I. Synthesis and crystal structure of trinuclear carboxylate complexes M3(μ3-O)(CF3COO)6L3 // Mendeleev Communications. 2004. Vol. 14. No. 4. pp. 141-143.

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TY - JOUR

DO - 10.1070/MC2004v014n04ABEH001953

UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n04ABEH001953

TI - Synthesis and crystal structure of trinuclear carboxylate complexes M3(μ3-O)(CF3COO)6L3

T2 - Mendeleev Communications

AU - Glazunova, Tatyana Yur'evna

AU - Boltalin, Alexander Ivanovich

AU - Troyanov, Sergey Igorevich

PY - 2004

DA - 2004/09/07

PB - Mendeleev Communications

SP - 141-143

IS - 4

VL - 14

ER -

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@article{2004_Glazunova,

author = {Tatyana Yur'evna Glazunova and Alexander Ivanovich Boltalin and Sergey Igorevich Troyanov},

title = {Synthesis and crystal structure of trinuclear carboxylate complexes M3(μ3-O)(CF3COO)6L3},

journal = {Mendeleev Communications},

year = {2004},

volume = {14},

publisher = {Mendeleev Communications},

month = {Sep},

url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n04ABEH001953},

number = {4},

pages = {141--143},

doi = {10.1070/MC2004v014n04ABEH001953}

}

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Glazunova, Tatyana Yur'evna, et al. “Synthesis and crystal structure of trinuclear carboxylate complexes M3(μ3-O)(CF3COO)6L3.” Mendeleev Communications, vol. 14, no. 4, Sep. 2004, pp. 141-143. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n04ABEH001953.

Abstract

Oxocarboxylate complexes of 3d metals containing a trinuclear neutral or cationic [M₃(μ3-O)(CF₃COO)₆L₃]⁰,+ unit (M = Cr, Fe; L = MeCOOH, H₂O, CF₃COO–, THF) were obtained by electrolytic dissolution of a metal in CF₃COOH or by a reaction of a metal (or its compound) with CF₃COOH; the crystal structures of three complexes were studied by single X-ray crystallography.

References

10.1016/S0065-2792(08)60041-2

Structures and Physical Properties of Polynuclear Carboxylates

Catterick J., Thornton P.

Advances in Inorganic Chemistry and Radiochemistry, 1977

10.1021/ic980001g

Kinetic Study on the Substitution of Dimethylacetamide for the Terminal Aqua Ligands in the Trinuclear Chromium(III) Complexes [Cr₃(μ₃-O)(μ-RCO₂)₆(H₂O)₃]⁺ (R = H, CH₃, CH₃CH₂, CH₂Cl, CHCl₂, CH₃OCH₂, (CH₃)₃C, CH₂ClCH₂, (CH₃CH₂)₂CH). Elucidation of the Mechanism from the Activation Volumes and the Substituent Effects of Bridging Carboxylate Ligands

Fujihara T., Aonahata J., Kumakura S., Nagasawa A., Murakami K., Ito T.

Inorganic Chemistry, 1998

10.1016/S0020-1693(01)00444-3

Mixed-terminal-ligand oxo-centered carboxylate-bridged trinuclear complexes: gas phase generation by means of electrospray ionization FT-ICR MS, condensed phase synthesis, and X-ray structure of K+[Cr3O(C6H5COO)6(F)2(H2O)]−·2(CH3)2CO

Palii S.P., Richardson D.E., Hansen M.L., Iversen B.B., Larsen F.K., Sı̂ngerean L., Timco G.A., Gerbeleu N.V., Jennings K.R., Eyler J.R.

Inorganica Chimica Acta, 2001

10.1016/S0020-1693(01)00793-9

Polynuclear chromium(III) carboxylates. 3. Cyclic and cubane type hexachromium acetates

Eshel M., Bino A.

Inorganica Chimica Acta, 2002

T. Yu. Glazunova, A. I. Boltalin, S. I. Troyanov, Koord. Khim., in press.

10.1070/MC2004v014n04ABEH001953_bib6

Ponomarev

Dokl. Akad. Nauk SSSR, 1982