Home / Publications / Synthesis and structure of the trinuclear complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2 and the binuclear complex Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 with the ‘Chinese lantern’ structure

Synthesis and structure of the trinuclear complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2 and the binuclear complex Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 with the ‘Chinese lantern’ structure

Èlina Vladimirovna Amel'chenkova 1
Èlina Vladimirovna Amel'chenkova
, 
Tatiana Olegovna Denisova 1
Tatiana Olegovna Denisova
, 
Sergey Evgen'evich Nefedov 1
Sergey Evgen'evich Nefedov
10.1070/MC2004v014n03ABEH001918
Published 2004-05-27
Communication , Volume 14, Issue 3, 103-104
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Amel'chenkova È. V., Denisova T. O., Nefedov S. E. Synthesis and structure of the trinuclear complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2 and the binuclear complex Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 with the ‘Chinese lantern’ structure // Mendeleev Communications. 2004. Vol. 14. No. 3. pp. 103-104.
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Amel'chenkova È. V., Denisova T. O., Nefedov S. E. Synthesis and structure of the trinuclear complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2 and the binuclear complex Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 with the ‘Chinese lantern’ structure // Mendeleev Communications. 2004. Vol. 14. No. 3. pp. 103-104.
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TY - JOUR
DO - 10.1070/MC2004v014n03ABEH001918
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n03ABEH001918
TI - Synthesis and structure of the trinuclear complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2 and the binuclear complex Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 with the ‘Chinese lantern’ structure
T2 - Mendeleev Communications
AU - Amel'chenkova, Èlina Vladimirovna
AU - Denisova, Tatiana Olegovna
AU - Nefedov, Sergey Evgen'evich
PY - 2004
DA - 2004/05/27
PB - Mendeleev Communications
SP - 103-104
IS - 3
VL - 14
ER -
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@article{2004_Amel'chenkova,
author = {Èlina Vladimirovna Amel'chenkova and Tatiana Olegovna Denisova and Sergey Evgen'evich Nefedov},
title = {Synthesis and structure of the trinuclear complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2 and the binuclear complex Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 with the ‘Chinese lantern’ structure},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n03ABEH001918},
number = {3},
pages = {103--104},
doi = {10.1070/MC2004v014n03ABEH001918}
}
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Amel'chenkova, Èlina Vladimirovna, et al. “Synthesis and structure of the trinuclear complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2 and the binuclear complex Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 with the ‘Chinese lantern’ structure.” Mendeleev Communications, vol. 14, no. 3, May. 2004, pp. 103-104. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n03ABEH001918.

Abstract

The treatment of the product of a thermal reaction of manganese(II) acetate tetrahydrate and trimethylacetic acid with triethylamine under reflux results in the unusual complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2, which, according to X-ray diffraction analysis, incorporates a linear Mn3 metal skeleton and four chelate-bridging trimethylacetate anions; a similar reaction at room temperature yields the Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 complex, which has a ‘Chinese lantern’ structure with the Mn…Mn distance equal to 3.1087(8) Å.

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