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Regioselective synthesis of pentathiepino-fused pyrroles and indoles

Lidia Sergeevna Konstantinova ¹

Lidia Sergeevna Konstantinova

Oleg Alexeevich Rakitin ¹

Oleg Alexeevich Rakitin

Charles W Rees ²

Charles W Rees

Stanislav Anatol'evich Amelichev ¹

Stanislav Anatol'evich Amelichev

¹ N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

² Department of Chemistry, Imperial College London, London, UK

10.1070/MC2004v014n03ABEH001912

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Published 2004-05-27

Communication , Volume 14, Issue 3, 91-92

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Konstantinova L. S. et al. Regioselective synthesis of pentathiepino-fused pyrroles and indoles // Mendeleev Communications. 2004. Vol. 14. No. 3. pp. 91-92.

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Konstantinova L. S., Rakitin O. A., Rees C. W., Amelichev S. A. Regioselective synthesis of pentathiepino-fused pyrroles and indoles // Mendeleev Communications. 2004. Vol. 14. No. 3. pp. 91-92.

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TY - JOUR

DO - 10.1070/MC2004v014n03ABEH001912

UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n03ABEH001912

TI - Regioselective synthesis of pentathiepino-fused pyrroles and indoles

T2 - Mendeleev Communications

AU - Konstantinova, Lidia Sergeevna

AU - Rakitin, Oleg Alexeevich

AU - Rees, Charles W

AU - Amelichev, Stanislav Anatol'evich

PY - 2004

DA - 2004/05/27

PB - Mendeleev Communications

SP - 91-92

IS - 3

VL - 14

ER -

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@article{2004_Konstantinova,

author = {Lidia Sergeevna Konstantinova and Oleg Alexeevich Rakitin and Charles W Rees and Stanislav Anatol'evich Amelichev},

title = {Regioselective synthesis of pentathiepino-fused pyrroles and indoles},

journal = {Mendeleev Communications},

year = {2004},

volume = {14},

publisher = {Mendeleev Communications},

month = {May},

url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n03ABEH001912},

number = {3},

pages = {91--92},

doi = {10.1070/MC2004v014n03ABEH001912}

}

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Konstantinova, Lidia Sergeevna, et al. “Regioselective synthesis of pentathiepino-fused pyrroles and indoles.” Mendeleev Communications, vol. 14, no. 3, May. 2004, pp. 91-92. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n03ABEH001912.

Abstract

Treatment of simple pyrroles, pyrrolidines and indoles with S₂Cl₂ and Dabco in chloroform at room temperature gives their fused pentathiepino derivatives 4, 6 and 8 in extensive cascade reactions; the reaction profile is changed and the regioselectivity enhanced when the S₂Cl₂ and Dabco are premixed and equilibrated before the heterocycle is added.