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Palladium-catalysed cross coupling of perfluoroalkenyl zinc reagents with 5-halo-6-azauracils

Hanna Wójtowicz-Rajchel 1
Hanna Wójtowicz-Rajchel
, 
Irena Bednarczyk 1
Irena Bednarczyk
, 
Andrzej Katrusiak 1
Andrzej Katrusiak
, 
Henryk Koroniak 1
Henryk Koroniak
10.1070/MC2004v014n02ABEH001888
Published 2004-04-14
Communication , Volume 14, Issue 2, 63-65
18
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Wójtowicz-Rajchel H. et al. Palladium-catalysed cross coupling of perfluoroalkenyl zinc reagents with 5-halo-6-azauracils // Mendeleev Communications. 2004. Vol. 14. No. 2. pp. 63-65.
GOST all authors (up to 50) Copy
Wójtowicz-Rajchel H., Bednarczyk I., Katrusiak A., Koroniak H. Palladium-catalysed cross coupling of perfluoroalkenyl zinc reagents with 5-halo-6-azauracils // Mendeleev Communications. 2004. Vol. 14. No. 2. pp. 63-65.
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TY - JOUR
DO - 10.1070/MC2004v014n02ABEH001888
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n02ABEH001888
TI - Palladium-catalysed cross coupling of perfluoroalkenyl zinc reagents with 5-halo-6-azauracils
T2 - Mendeleev Communications
AU - Wójtowicz-Rajchel, Hanna
AU - Bednarczyk, Irena
AU - Katrusiak, Andrzej
AU - Koroniak, Henryk
PY - 2004
DA - 2004/04/14
PB - Mendeleev Communications
SP - 63-65
IS - 2
VL - 14
ER -
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@article{2004_Wójtowicz-Rajchel,
author = {Hanna Wójtowicz-Rajchel and Irena Bednarczyk and Andrzej Katrusiak and Henryk Koroniak},
title = {Palladium-catalysed cross coupling of perfluoroalkenyl zinc reagents with 5-halo-6-azauracils},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n02ABEH001888},
number = {2},
pages = {63--65},
doi = {10.1070/MC2004v014n02ABEH001888}
}
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Wójtowicz-Rajchel, Hanna, et al. “Palladium-catalysed cross coupling of perfluoroalkenyl zinc reagents with 5-halo-6-azauracils.” Mendeleev Communications, vol. 14, no. 2, Apr. 2004, pp. 63-65. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n02ABEH001888.

Abstract

The title reactions of 1,3-dimethyl-5-halo-6-azauracils with perfluoroalkenylzinc reagents [CF2=CFZnI and CF3C(ZnBr)=CF2] give not only corresponding alkenes but also, unexpectedly, a hexafluoroalkane derivative.

References

1.
10.1070/MC2004v014n02ABEH001888_bib1
Filler
Organofluorine Compounds in Medicinal and Biomedical Applications, 1993
3.
10.1070/MC2004v014n02ABEH001888_bib3
Beletskaya
Izv. Akad. Nauk. SSSR, Ser. Khim., 1985
6.
Synthesis of some 5-perfluoroalkenyl derivatives of uracil
Koroniak H., Karwatka P., Pluskota D., Fiedorow P., Jankowski A.
Journal of Fluorine Chemistry, 1995
7.
Novel Ring Contraction of 6-Azauracil Derivatives
Wojtowicz-Rajchel H., Szczepkowska-Sztolcman J., Katrusiak A., Golankiewicz K.
Tetrahedron, 2000
8.
Reactions of π-electron rich 1,2,4-triazines with organolithium nucleophiles
Szczepkowska-Sztolcman J., Katrusiak A., Wójtowicz-Rajchel H., Golankiewicz K.
Journal of the Chemical Society Perkin Transactions 1, 2002
9.
Synthesis and antiviral properties of 5-(2-substituted vinyl)-6-aza-2'-deoxyuridines
Mitchell W.L., Ravenscroft P., Hill M.L., Knutsen L.J., Judkins B.D., Newton R.F., Scopes D.I.
Journal of Medicinal Chemistry, 1986
10.
10.1070/MC2004v014n02ABEH001888_bib10
Spawn
Bull. Soc. Chim. Fr., 1986
11.
10.1070/MC2004v014n02ABEH001888_bib11
Cheburkov
Izv. Akad. Nauk SSSR, Ser. Khim., 1967
12.
Mechanism of the Stille Reaction Catalyzed by Palladium Ligated to Arsine Ligand:  PhPdI(AsPh3)(DMF) Is the Species Reacting with Vinylstannane in DMF
Amatore C., Bahsoun A.A., Jutand A., Meyer G., Ndedi Ntepe A., Ricard L.
Journal of the American Chemical Society, 2003
13.
Amatore C., Carré E., Jutand A., Miller L.L., Sebastiani G.V., Francis G.W., Szúnyog J., Långström B.
Acta Chemica Scandinavica, 2008