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Catalytic methoxycarbonylation of alkoxyallenes

Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
, 
Anastasiya Grigor'evna Mal'kina 1
Anastasiya Grigor'evna Mal'kina
, 
Ravilya Nizametdinovna Kudyakova 1
Ravilya Nizametdinovna Kudyakova
, 
Ol'ga Anatol'evna Tarasova 1
Ol'ga Anatol'evna Tarasova
, 
Valentina Vasil'evna Nosyreva 1
Valentina Vasil'evna Nosyreva
, 
Andrei Valer'evich Afonin 1
Andrei Valer'evich Afonin
10.1070/MC2004v014n02ABEH001878
Published 2004-04-14
Communication , Volume 14, Issue 2, 61-63
3
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Trofimov B. A. et al. Catalytic methoxycarbonylation of alkoxyallenes // Mendeleev Communications. 2004. Vol. 14. No. 2. pp. 61-63.
GOST all authors (up to 50) Copy
Trofimov B. A., Mal'kina A. G., Kudyakova R. N., Tarasova O. A., Nosyreva V. V., Afonin A. V. Catalytic methoxycarbonylation of alkoxyallenes // Mendeleev Communications. 2004. Vol. 14. No. 2. pp. 61-63.
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TY - JOUR
DO - 10.1070/MC2004v014n02ABEH001878
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n02ABEH001878
TI - Catalytic methoxycarbonylation of alkoxyallenes
T2 - Mendeleev Communications
AU - Trofimov, Boris Aleksandrovich
AU - Mal'kina, Anastasiya Grigor'evna
AU - Kudyakova, Ravilya Nizametdinovna
AU - Tarasova, Ol'ga Anatol'evna
AU - Nosyreva, Valentina Vasil'evna
AU - Afonin, Andrei Valer'evich
PY - 2004
DA - 2004/04/14
PB - Mendeleev Communications
SP - 61-63
IS - 2
VL - 14
ER -
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@article{2004_Trofimov,
author = {Boris Aleksandrovich Trofimov and Anastasiya Grigor'evna Mal'kina and Ravilya Nizametdinovna Kudyakova and Ol'ga Anatol'evna Tarasova and Valentina Vasil'evna Nosyreva and Andrei Valer'evich Afonin},
title = {Catalytic methoxycarbonylation of alkoxyallenes},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n02ABEH001878},
number = {2},
pages = {61--63},
doi = {10.1070/MC2004v014n02ABEH001878}
}
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Trofimov, Boris Aleksandrovich, et al. “Catalytic methoxycarbonylation of alkoxyallenes.” Mendeleev Communications, vol. 14, no. 2, Apr. 2004, pp. 61-63. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n02ABEH001878.

Abstract

Methoxyallene reacts with carbon monoxide in the PdCl2–CuCl2–NaHCO3 (NaHCO3/NaOAc) system in MeOH to afford methyl 2-(dimethoxymethyl)acrylate and 2-chloro-3,3-dimethoxyprop-1-ene; the third product, 2-chloro-1-methoxy-2-propenyl acetate, appears when NaHCO3–NaOAc is used as a buffer component.

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