Home / Publications / Hexa- and heptasubstitution in the interaction of octafluoronaphthalene with lithium dialkylamides: a new approach to the naphthalene ‘proton sponges’

Hexa- and heptasubstitution in the interaction of octafluoronaphthalene with lithium dialkylamides: a new approach to the naphthalene ‘proton sponges’

Vladimir Igorevich Sorokin 1
Vladimir Igorevich Sorokin
, 
Valery Anatol'evich Ozeryanskii 1
Valery Anatol'evich Ozeryanskii
, 
Alexander Fedorovich Pozharskii 1
Alexander Fedorovich Pozharskii
, 
Zoya Aleksandrovna Starikova 2
Zoya Aleksandrovna Starikova
10.1070/MC2004v014n01ABEH001852
Published 2004-03-05
Communication , Volume 14, Issue 1, 14-16
6
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Sorokin V. I. et al. Hexa- and heptasubstitution in the interaction of octafluoronaphthalene with lithium dialkylamides: a new approach to the naphthalene ‘proton sponges’ // Mendeleev Communications. 2004. Vol. 14. No. 1. pp. 14-16.
GOST all authors (up to 50) Copy
Sorokin V. I., Ozeryanskii V. A., Pozharskii A. F., Starikova Z. A. Hexa- and heptasubstitution in the interaction of octafluoronaphthalene with lithium dialkylamides: a new approach to the naphthalene ‘proton sponges’ // Mendeleev Communications. 2004. Vol. 14. No. 1. pp. 14-16.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2004v014n01ABEH001852
UR - https://mendcomm.colab.ws/publications/10.1070/MC2004v014n01ABEH001852
TI - Hexa- and heptasubstitution in the interaction of octafluoronaphthalene with lithium dialkylamides: a new approach to the naphthalene ‘proton sponges’
T2 - Mendeleev Communications
AU - Sorokin, Vladimir Igorevich
AU - Ozeryanskii, Valery Anatol'evich
AU - Pozharskii, Alexander Fedorovich
AU - Starikova, Zoya Aleksandrovna
PY - 2004
DA - 2004/03/05
PB - Mendeleev Communications
SP - 14-16
IS - 1
VL - 14
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2004_Sorokin,
author = {Vladimir Igorevich Sorokin and Valery Anatol'evich Ozeryanskii and Alexander Fedorovich Pozharskii and Zoya Aleksandrovna Starikova},
title = {Hexa- and heptasubstitution in the interaction of octafluoronaphthalene with lithium dialkylamides: a new approach to the naphthalene ‘proton sponges’},
journal = {Mendeleev Communications},
year = {2004},
volume = {14},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2004v014n01ABEH001852},
number = {1},
pages = {14--16},
doi = {10.1070/MC2004v014n01ABEH001852}
}
MLA
Cite this
MLA Copy
Sorokin, Vladimir Igorevich, et al. “Hexa- and heptasubstitution in the interaction of octafluoronaphthalene with lithium dialkylamides: a new approach to the naphthalene ‘proton sponges’.” Mendeleev Communications, vol. 14, no. 1, Mar. 2004, pp. 14-16. https://mendcomm.colab.ws/publications/10.1070/MC2004v014n01ABEH001852.

Abstract

The reaction of octafluoronaphthalene with lithium dimethylamide, pyrrolidide and piperidide was performed to synthesise polykis(dialkylamino)naphthalenes with up to seven dialkylamino groups as new strongly basic naphthalene ‘proton sponges’.

References

1.
Strain effects on amine basicities
Alder R.W.
Chemical Reviews, 1989
2.
Proton sponges
Llamas-Saiz A.L., Foces-Foces C., Elguero J.
Journal of Molecular Structure, 1994
3.
Naphthalene 'proton sponges'
Pozharskii A.F.
Russian Chemical Reviews, 1998
4.
Azole chemistry. X. Silaazoles
Alper H., Wolin M.S.
Journal of Organic Chemistry, 1975
5.
Catalytic Activity of Proton Sponge: Application to Knoevenagel Condensation Reactions
Rodriguez I., Sastre G., Corma A., Iborra S.
Journal of Catalysis, 1999
6.
The Development of the First Catalyzed Reaction of Ketenes and Imines:  Catalytic, Asymmetric Synthesis of β-Lactams
Taggi A.E., Hafez A.M., Wack H., Young B., Ferraris D., Lectka T.
Journal of the American Chemical Society, 2002