Home / Publications / Unexpected reactivity of 3-ethylsulfonyl-1,2,4-triazines with B12H11SH⌉2–: first examples of the synthesis of boron-centered as-triazines and thioesters of ethyl sulfinic acid

Unexpected reactivity of 3-ethylsulfonyl-1,2,4-triazines with B12H11SH⌉2–: first examples of the synthesis of boron-centered as-triazines and thioesters of ethyl sulfinic acid

Yurii Alexeevich Azev 1
Yurii Alexeevich Azev
, 
Enno Lork 2
Enno Lork
, 
Thomas Duelcks 2
Thomas Duelcks
, 
Detlef Gabel 2
Detlef Gabel
1 Ural Scientific Research Institute of Technology of Medical Preparations, Ekaterinburg, Russian Federation
10.1070/MC2003v013n06ABEH001843
Published 2003-12-26
Communication , Volume 13, Issue 6, 262-264
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Azev Y. A. et al. Unexpected reactivity of 3-ethylsulfonyl-1,2,4-triazines with B12H11SH⌉2–: first examples of the synthesis of boron-centered as-triazines and thioesters of ethyl sulfinic acid // Mendeleev Communications. 2003. Vol. 13. No. 6. pp. 262-264.
GOST all authors (up to 50) Copy
Azev Y. A., Lork E., Duelcks T., Gabel D. Unexpected reactivity of 3-ethylsulfonyl-1,2,4-triazines with B12H11SH⌉2–: first examples of the synthesis of boron-centered as-triazines and thioesters of ethyl sulfinic acid // Mendeleev Communications. 2003. Vol. 13. No. 6. pp. 262-264.
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TY - JOUR
DO - 10.1070/MC2003v013n06ABEH001843
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n06ABEH001843
TI - Unexpected reactivity of 3-ethylsulfonyl-1,2,4-triazines with B12H11SH⌉2–: first examples of the synthesis of boron-centered as-triazines and thioesters of ethyl sulfinic acid
T2 - Mendeleev Communications
AU - Azev, Yurii Alexeevich
AU - Lork, Enno
AU - Duelcks, Thomas
AU - Gabel, Detlef
PY - 2003
DA - 2003/12/26
PB - Mendeleev Communications
SP - 262-264
IS - 6
VL - 13
ER -
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@article{2003_Azev,
author = {Yurii Alexeevich Azev and Enno Lork and Thomas Duelcks and Detlef Gabel},
title = {Unexpected reactivity of 3-ethylsulfonyl-1,2,4-triazines with B12H11SH⌉2–: first examples of the synthesis of boron-centered as-triazines and thioesters of ethyl sulfinic acid},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n06ABEH001843},
number = {6},
pages = {262--264},
doi = {10.1070/MC2003v013n06ABEH001843}
}
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Azev, Yurii Alexeevich, et al. “Unexpected reactivity of 3-ethylsulfonyl-1,2,4-triazines with B12H11SH⌉2–: first examples of the synthesis of boron-centered as-triazines and thioesters of ethyl sulfinic acid.” Mendeleev Communications, vol. 13, no. 6, Dec. 2003, pp. 262-264. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n06ABEH001843.

Abstract

The reaction of 3-ethylsulfonyl-5-methylamino-6-methylcarboxamido-1,2,4-triazine 1 with B12H11SH⌉2– yields the boron-containing derivatives of 1,2,4-triazine 3. The interaction of 5,7-dimethyl-5,6,7,8-tetrahydropyrimido[4,5-e][1,2,4]triazine-6,8-dione 2 with mercaptoborane B12H11SH⌉2– gives boron-containing thiosulfinate 4 and bis(heteryl) ether 5.

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