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An unexpected transformation of 3,4-diacylfuroxans into 3-acyl-4-acylaminofurazans in the reaction with nitriles

Ilya V Seregin 1
Ilya V Seregin
, 
Igor Vyacheslavovich Ovchinnikov 1
Igor Vyacheslavovich Ovchinnikov
, 
Nina Nikolaevna Makhova 1
Nina Nikolaevna Makhova
, 
Denis Victorovich Lyubetsky 2
Denis Victorovich Lyubetsky
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
10.1070/MC2003v013n05ABEH001811
Published 2003-11-04
Communication , Volume 13, Issue 5, 230-232
12
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Seregin I. V. et al. An unexpected transformation of 3,4-diacylfuroxans into 3-acyl-4-acylaminofurazans in the reaction with nitriles // Mendeleev Communications. 2003. Vol. 13. No. 5. pp. 230-232.
GOST all authors (up to 50) Copy
Seregin I. V., Ovchinnikov I. V., Makhova N. N., Lyubetsky D. V., Lyssenko K. A. An unexpected transformation of 3,4-diacylfuroxans into 3-acyl-4-acylaminofurazans in the reaction with nitriles // Mendeleev Communications. 2003. Vol. 13. No. 5. pp. 230-232.
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TY - JOUR
DO - 10.1070/MC2003v013n05ABEH001811
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n05ABEH001811
TI - An unexpected transformation of 3,4-diacylfuroxans into 3-acyl-4-acylaminofurazans in the reaction with nitriles
T2 - Mendeleev Communications
AU - Seregin, Ilya V
AU - Ovchinnikov, Igor Vyacheslavovich
AU - Makhova, Nina Nikolaevna
AU - Lyubetsky, Denis Victorovich
AU - Lyssenko, Konstantin Alexandrovich
PY - 2003
DA - 2003/11/04
PB - Mendeleev Communications
SP - 230-232
IS - 5
VL - 13
ER -
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@article{2003_Seregin,
author = {Ilya V Seregin and Igor Vyacheslavovich Ovchinnikov and Nina Nikolaevna Makhova and Denis Victorovich Lyubetsky and Konstantin Alexandrovich Lyssenko},
title = {An unexpected transformation of 3,4-diacylfuroxans into 3-acyl-4-acylaminofurazans in the reaction with nitriles},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n05ABEH001811},
number = {5},
pages = {230--232},
doi = {10.1070/MC2003v013n05ABEH001811}
}
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Seregin, Ilya V., et al. “An unexpected transformation of 3,4-diacylfuroxans into 3-acyl-4-acylaminofurazans in the reaction with nitriles.” Mendeleev Communications, vol. 13, no. 5, Nov. 2003, pp. 230-232. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n05ABEH001811.

Abstract

The reaction of 3,4-diacyl-1,2,5-oxadiazole 2-oxides (furoxans) with activated nitriles in ionic liquids and in ethanol unexpectedly resulted in 3-acyl-4-acylamino-1,2,5-oxadiazoles (furazans); a possible mechanism of this reaction is proposed.

References

1.
Seregin I.V., Batog L.V., Makhova N.N.
Mendeleev Communications, 2002
3.
The use of new ionic liquids in two-phase catalytic hydrogenation reaction by rhodium complexes
Suarez P.A., Dullius J.E., Einloft S., De Souza R.F., Dupont J.
Polyhedron, 1996
5.
10.1070/MC2003v013n05ABEH001811_bib5
2003
6.
10.1070/MC2003v013n05ABEH001811_bib6
Grundmann
The Nitrile Oxides, 1971
8.
Reaction of 3,4-disubstituted 1,2,5-oxadiazole 2-oxides with dipolarophiles
Shimizu T., Hayashi Y., Taniguchi T., Teramura K.
Tetrahedron, 1985
9.
Ovchinnikov I.V., Popov N.A., Makhova N.N., Khmel’nitskii L.I., Shlyapochnikov V.A.
Mendeleev Communications, 1995
10.
10.1070/MC2003v013n05ABEH001811_bib10
Cusmano
Gazz. Chim. Ital., 1958