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Thermal rearrangements of 3-substituted 4-(3-ethoxycarbonylthioureido)-1,2,5-oxadiazole 2-oxides

Sergey Igorevich Molotov 1
Sergey Igorevich Molotov
, 
Alexander Sergeyevich Kulikov 1
Alexander Sergeyevich Kulikov
, 
Nina Nikolaevna Makhova 1
Nina Nikolaevna Makhova
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
10.1070/MC2003v013n04ABEH001792
Published 2003-09-02
Communication , Volume 13, Issue 4, 188-190
11
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Molotov S. I. et al. Thermal rearrangements of 3-substituted 4-(3-ethoxycarbonylthioureido)-1,2,5-oxadiazole 2-oxides // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 188-190.
GOST all authors (up to 50) Copy
Molotov S. I., Kulikov A. S., Makhova N. N., Lyssenko K. A. Thermal rearrangements of 3-substituted 4-(3-ethoxycarbonylthioureido)-1,2,5-oxadiazole 2-oxides // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 188-190.
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TY - JOUR
DO - 10.1070/MC2003v013n04ABEH001792
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001792
TI - Thermal rearrangements of 3-substituted 4-(3-ethoxycarbonylthioureido)-1,2,5-oxadiazole 2-oxides
T2 - Mendeleev Communications
AU - Molotov, Sergey Igorevich
AU - Kulikov, Alexander Sergeyevich
AU - Makhova, Nina Nikolaevna
AU - Lyssenko, Konstantin Alexandrovich
PY - 2003
DA - 2003/09/02
PB - Mendeleev Communications
SP - 188-190
IS - 4
VL - 13
ER -
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@article{2003_Molotov,
author = {Sergey Igorevich Molotov and Alexander Sergeyevich Kulikov and Nina Nikolaevna Makhova and Konstantin Alexandrovich Lyssenko},
title = {Thermal rearrangements of 3-substituted 4-(3-ethoxycarbonylthioureido)-1,2,5-oxadiazole 2-oxides},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001792},
number = {4},
pages = {188--190},
doi = {10.1070/MC2003v013n04ABEH001792}
}
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Molotov, Sergey Igorevich, et al. “Thermal rearrangements of 3-substituted 4-(3-ethoxycarbonylthioureido)-1,2,5-oxadiazole 2-oxides.” Mendeleev Communications, vol. 13, no. 4, Sep. 2003, pp. 188-190. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001792.

Abstract

New thermally induced rearrangements in the furoxan series have been found: transformation of 3-(R)-substituted 4-(3-ethoxy-carbonylthioureido)-1,2,5-oxadiazole 2-oxides (furoxans) into derivatives of 5-amino-3-(α-nitroalkyl)-1,2,4-thiadiazole for R = Me, Ph, MeCO and into (5-amino-1,2,4-thiadiazol-3-yl)nitroformaldehyde arylhydrazones for R = N=N–Ar.

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