Home / Publications / 1,2,4-Triazinylcarboranes: a new approach to the synthesis and the crystal structures of 1-(3,6-ditolyl-1,2,4-triazin-5-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane and 1,7-bis[6-phenyl-3-(4-chlorophenyl)-1,2,4-triazin-5-yl]-1,7-dicarba-closo-dodecaborane

1,2,4-Triazinylcarboranes: a new approach to the synthesis and the crystal structures of 1-(3,6-ditolyl-1,2,4-triazin-5-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane and 1,7-bis[6-phenyl-3-(4-chlorophenyl)-1,2,4-triazin-5-yl]-1,7-dicarba-closo-dodecaborane

Oleg Nikolaevich Chupakhin 1
Oleg Nikolaevich Chupakhin
, 
Anton Mikhaylovich Prokhorov 1
Anton Mikhaylovich Prokhorov
, 
Dmitry Nikolaevich Kozhevnikov 1
Dmitry Nikolaevich Kozhevnikov
, 
Vladimir Leonidovich Rusinov 1
Vladimir Leonidovich Rusinov
, 
Valery Nikolaevich Kalinin 2
Valery Nikolaevich Kalinin
, 
Valentina Antonovna Ol'shevskaya 2
Valentina Antonovna Ol'shevskaya
, 
Ivan Vladimirovich Glukhov 2
Ivan Vladimirovich Glukhov
, 
Mikhail Yuvenal'evich Antipin 2
Mikhail Yuvenal'evich Antipin
10.1070/MC2003v013n04ABEH001773
Published 2003-09-02
Communication , Volume 13, Issue 4, 165-167
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Chupakhin O. N. et al. 1,2,4-Triazinylcarboranes: a new approach to the synthesis and the crystal structures of 1-(3,6-ditolyl-1,2,4-triazin-5-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane and 1,7-bis[6-phenyl-3-(4-chlorophenyl)-1,2,4-triazin-5-yl]-1,7-dicarba-closo-dodecaborane // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 165-167.
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Chupakhin O. N., Prokhorov A. M., Kozhevnikov D. N., Rusinov V. L., Kalinin V. N., Ol'shevskaya V. A., Glukhov I. V., Antipin M. Y. 1,2,4-Triazinylcarboranes: a new approach to the synthesis and the crystal structures of 1-(3,6-ditolyl-1,2,4-triazin-5-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane and 1,7-bis[6-phenyl-3-(4-chlorophenyl)-1,2,4-triazin-5-yl]-1,7-dicarba-closo-dodecaborane // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 165-167.
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TY - JOUR
DO - 10.1070/MC2003v013n04ABEH001773
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001773
TI - 1,2,4-Triazinylcarboranes: a new approach to the synthesis and the crystal structures of 1-(3,6-ditolyl-1,2,4-triazin-5-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane and 1,7-bis[6-phenyl-3-(4-chlorophenyl)-1,2,4-triazin-5-yl]-1,7-dicarba-closo-dodecaborane
T2 - Mendeleev Communications
AU - Chupakhin, Oleg Nikolaevich
AU - Prokhorov, Anton Mikhaylovich
AU - Kozhevnikov, Dmitry Nikolaevich
AU - Rusinov, Vladimir Leonidovich
AU - Kalinin, Valery Nikolaevich
AU - Ol'shevskaya, Valentina Antonovna
AU - Glukhov, Ivan Vladimirovich
AU - Antipin, Mikhail Yuvenal'evich
PY - 2003
DA - 2003/09/02
PB - Mendeleev Communications
SP - 165-167
IS - 4
VL - 13
ER -
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@article{2003_Chupakhin,
author = {Oleg Nikolaevich Chupakhin and Anton Mikhaylovich Prokhorov and Dmitry Nikolaevich Kozhevnikov and Vladimir Leonidovich Rusinov and Valery Nikolaevich Kalinin and Valentina Antonovna Ol'shevskaya and Ivan Vladimirovich Glukhov and Mikhail Yuvenal'evich Antipin},
title = {1,2,4-Triazinylcarboranes: a new approach to the synthesis and the crystal structures of 1-(3,6-ditolyl-1,2,4-triazin-5-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane and 1,7-bis[6-phenyl-3-(4-chlorophenyl)-1,2,4-triazin-5-yl]-1,7-dicarba-closo-dodecaborane},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001773},
number = {4},
pages = {165--167},
doi = {10.1070/MC2003v013n04ABEH001773}
}
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Chupakhin, Oleg Nikolaevich, et al. “1,2,4-Triazinylcarboranes: a new approach to the synthesis and the crystal structures of 1-(3,6-ditolyl-1,2,4-triazin-5-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane and 1,7-bis[6-phenyl-3-(4-chlorophenyl)-1,2,4-triazin-5-yl]-1,7-dicarba-closo-dodecaborane.” Mendeleev Communications, vol. 13, no. 4, Sep. 2003, pp. 165-167. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001773.

Abstract

The SNH reactions of the lithio derivatives of 1,2- or 1,7-dicarba-closo-dodecaboranes with 1,2,4-triazine 4-oxides represent a versatile synthetic approach to carboranes bearing heteroaromatic substituents.

References

2.
The Chemistry of Neutron Capture Therapy
Soloway A.H., Tjarks W., Barnum B.A., Rong F., Barth R.F., Codogni I.M., Wilson J.G.
Chemical Reviews, 1998
4.
10.1070/MC2003v013n04ABEH001773_bib4
Tjarks
J. Orgnomet. Chem., 2000
5.
The medicinal chemistry of carboranes
Valliant J.F., Guenther K.J., King A.S., Morel P., Schaffer P., Sogbein O.O., Stephenson K.A.
Coordination Chemistry Reviews, 2002
7.
C-arylation and C-heteroarylation of icosahedral carboranes via their copper(I) derivatives
Coult R., Fox M.A., Gill W.R., Herbertson P.L., MacBride J.A., Wade K.
Journal of Organometallic Chemistry, 1993
8.
Preparation of C-2-pyridyl derivatives of icosahedral carboranes via copper(I) intermediates
Gill W.R., Herbertson P.L., MacBride J.A., Wade K.
Journal of Organometallic Chemistry, 1996
9.
10.1070/MC2003v013n04ABEH001773_bib8_1
Drygina
Khim. Geterotsikl. Soedin., 1977
10.
10.1070/MC2003v013n04ABEH001773_bib8_2
Drygina
Khim. Geterotsikl. Soedin., 1983
11.
10.1070/MC2003v013n04ABEH001773_bib9
Drygina
Khim. Geterotsikl. Soedin., 1981
12.
10.1070/MC2003v013n04ABEH001773_bib10
Chupakhin
Nucleophilic Aromatic Substitution of Hydrogen, 1994
14.
Deoxygenative vs. Vicarious Nucleophilic Substitution of Hydrogen in Reactions of 1,2,4-Triazine 4-Oxides with α-Halocarbanions
Kozhevnikov D., Rusinov V., Chupakhin O., Makosza M., Rykowski A., Wolinska E.
European Journal of Organic Chemistry, 2002