Home / Publications / Synthesis and structure of the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF (Hdmpz = 3,5-dimethylpyrazole)

Synthesis and structure of the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF (Hdmpz = 3,5-dimethylpyrazole)

Tatiana Olegovna Denisova 1
Tatiana Olegovna Denisova
, 
Sergey Evgen'evich Nefedov 1
Sergey Evgen'evich Nefedov
10.1070/MC2003v013n04ABEH001771
Published 2003-09-02
Communication , Volume 13, Issue 4, 161-162
4
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Denisova T. O., Nefedov S. E. Synthesis and structure of the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF (Hdmpz = 3,5-dimethylpyrazole) // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 161-162.
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Denisova T. O., Nefedov S. E. Synthesis and structure of the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF (Hdmpz = 3,5-dimethylpyrazole) // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 161-162.
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TY - JOUR
DO - 10.1070/MC2003v013n04ABEH001771
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001771
TI - Synthesis and structure of the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF (Hdmpz = 3,5-dimethylpyrazole)
T2 - Mendeleev Communications
AU - Denisova, Tatiana Olegovna
AU - Nefedov, Sergey Evgen'evich
PY - 2003
DA - 2003/09/02
PB - Mendeleev Communications
SP - 161-162
IS - 4
VL - 13
ER -
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@article{2003_Denisova,
author = {Tatiana Olegovna Denisova and Sergey Evgen'evich Nefedov},
title = {Synthesis and structure of the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF (Hdmpz = 3,5-dimethylpyrazole)},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001771},
number = {4},
pages = {161--162},
doi = {10.1070/MC2003v013n04ABEH001771}
}
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Denisova, Tatiana Olegovna, and Sergey Evgen'evich Nefedov. “Synthesis and structure of the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF (Hdmpz = 3,5-dimethylpyrazole).” Mendeleev Communications, vol. 13, no. 4, Sep. 2003, pp. 161-162. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001771.

Abstract

The reaction of Co2(μ-OOCBut)2(Hdmpz)4(MeCN)2[OS(O)2CF3]2 (Hdmpz = 3,5-dimethylpyrazole) with water in THF at room temperature gave the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF, which were characterised using X-ray diffraction analysis.

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