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Solvent-free Pd-catalysed N-arylation of amines, amides and diaza-18-crown-6

Galina Anisimovna Artamkina 1
Galina Anisimovna Artamkina
, 
Maria V Ermolina 1
Maria V Ermolina
, 
10.1070/MC2003v013n04ABEH001753
Published 2003-09-02
Communication , Volume 13, Issue 4, 158-160
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Artamkina G. A., Ermolina M. V., Beletskaya I. P. Solvent-free Pd-catalysed N-arylation of amines, amides and diaza-18-crown-6 // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 158-160.
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Artamkina G. A., Ermolina M. V., Beletskaya I. P. Solvent-free Pd-catalysed N-arylation of amines, amides and diaza-18-crown-6 // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 158-160.
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TY - JOUR
DO - 10.1070/MC2003v013n04ABEH001753
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001753
TI - Solvent-free Pd-catalysed N-arylation of amines, amides and diaza-18-crown-6
T2 - Mendeleev Communications
AU - Artamkina, Galina Anisimovna
AU - Ermolina, Maria V
AU - Beletskaya, Irina Petrovna
PY - 2003
DA - 2003/09/02
PB - Mendeleev Communications
SP - 158-160
IS - 4
VL - 13
ER -
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@article{2003_Artamkina,
author = {Galina Anisimovna Artamkina and Maria V Ermolina and Irina Petrovna Beletskaya},
title = {Solvent-free Pd-catalysed N-arylation of amines, amides and diaza-18-crown-6},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001753},
number = {4},
pages = {158--160},
doi = {10.1070/MC2003v013n04ABEH001753}
}
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Artamkina, Galina Anisimovna, et al. “Solvent-free Pd-catalysed N-arylation of amines, amides and diaza-18-crown-6.” Mendeleev Communications, vol. 13, no. 4, Sep. 2003, pp. 158-160. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001753.

Abstract

The N-arylation of amines, amides and diaza-18-crown-6 with weakly activated aryl bromides catalysed by Pd0/L and the arylation of pyrrolidone-2 with 2-bromothiophene catalysed by CuI/1,2-di(methylamino)cyclohexane can be performed in the presence of graphite at 60–100 °C without solvent to give arylation products in good yields (60–78%).

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