Home / Publications / New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals

New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals

Konstantin V Shuvaev 1
Konstantin V Shuvaev
, 
Victor Andreevich Bagryansky 2
Victor Andreevich Bagryansky
, 
Nina Pavlovna Gritsan 2
Nina Pavlovna Gritsan
, 
Alexander Yur'evich Makarov 3
Alexander Yur'evich Makarov
, 
Yuri Nikolaevich Molin 2
Yuri Nikolaevich Molin
, 
Andrey Viktorovich Zibarev 3
Andrey Viktorovich Zibarev
10.1070/MC2003v013n04ABEH001741
Published 2003-09-02
Communication , Volume 13, Issue 4, 178-179
22
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Shuvaev K. V. et al. New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 178-179.
GOST all authors (up to 50) Copy
Shuvaev K. V., Bagryansky V. A., Gritsan N. P., Makarov A. Y., Molin Y. N., Zibarev A. V. New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 178-179.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2003v013n04ABEH001741
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001741
TI - New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals
T2 - Mendeleev Communications
AU - Shuvaev, Konstantin V
AU - Bagryansky, Victor Andreevich
AU - Gritsan, Nina Pavlovna
AU - Makarov, Alexander Yur'evich
AU - Molin, Yuri Nikolaevich
AU - Zibarev, Andrey Viktorovich
PY - 2003
DA - 2003/09/02
PB - Mendeleev Communications
SP - 178-179
IS - 4
VL - 13
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2003_Shuvaev,
author = {Konstantin V Shuvaev and Victor Andreevich Bagryansky and Nina Pavlovna Gritsan and Alexander Yur'evich Makarov and Yuri Nikolaevich Molin and Andrey Viktorovich Zibarev},
title = {New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001741},
number = {4},
pages = {178--179},
doi = {10.1070/MC2003v013n04ABEH001741}
}
MLA
Cite this
MLA Copy
Shuvaev, Konstantin V., et al. “New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals.” Mendeleev Communications, vol. 13, no. 4, Sep. 2003, pp. 178-179. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001741.

Abstract

Both thermolysis and photolysis of 1,2,4λ4δ2,3,5- and 1,3λ4δ2,5,2,4-benzotrithiadiazepines in hydrocarbon solvents yielded stable 1,2,3- and 1,3,2-benzodithiazolyls, which can be considered as a particular case of a previously unmentioned trend of neutral polysulfur–nitrogen heterocycles to form thiazyl π-radicals.

References

2.
Bagryansky V.A., Vlasyuk I.V., Gatilov Y.V., Makarov A.Y., Molin Y.N., Shcherbukhin V.V., Zibarev A.V.
Mendeleev Communications, 2000
3.
1,2,3-Benzodithiazolyl radicals formed by thermolysis and photolysis of 1,3,2,4-benzodithiadiazines
Vlasyuk I.V., Bagryansky V.A., Gritsan N.P., Molin Y.N., Yu. Makarov A., Gatilov Y.V., Shcherbukhin V.V., Zibarev A.V.
Physical Chemistry Chemical Physics, 2001
4.
10.1070/MC2003v013n04ABEH001741_bib4
Gritsan
Izv. Akad. Nauk, Ser. Khim., 2001
6.
1,2,4,3,5-Benzotrithiadiazepine and its unexpected hydrolysis to unusual 7H,14H-dibenzo[d,i][1,2,6,7,3,8]tetrathiadiazecine
Makarov A.Y., Shakirov M.M., Bagryanskaya I.Y., Gatilov Y.V., Zibarev A.V., Shuvaev K.V.
Chemical Communications, 2001
7.
Organic heterocyclothiazenes. Part 4. Chemistry of 1,3,5,2,4-trithiadiazepines
Morris J.L., Rees C.W.
Journal of the Chemical Society Perkin Transactions 1, 1987
8.
Gas phase electron resonance spectrum of NS
Carrington A., Howard B.J., Levy D.H., Robertson J.C.
Molecular Physics, 1968
10.
Electron spin resonance study of CH3CNSSN˙, C6H5CNSSN˙, and SNSSN˙+free radicals
Fairhurst S.A., Johnson K.M., Sutcliffe L.H., Preston K.F., Banister A.J., Hauptman Z.V., Passmore J.
Journal of the Chemical Society Dalton Transactions, 1986