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Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine

Maria Vladimirovna Lobanova 1
Maria Vladimirovna Lobanova
, 
Konstantin Petrovich Bryliakov 1
Konstantin Petrovich Bryliakov
, 
Eduard Anatol'evich Duban 1
Eduard Anatol'evich Duban
, 
Evgenii Pavlovich Talsi 1
Evgenii Pavlovich Talsi
10.1070/MC2003v013n04ABEH001727
Published 2003-09-02
Communication , Volume 13, Issue 4, 175-177
16
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Lobanova M. V. et al. Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 175-177.
GOST all authors (up to 50) Copy
Lobanova M. V., Bryliakov K. P., Duban E. A., Talsi E. P. Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine // Mendeleev Communications. 2003. Vol. 13. No. 4. pp. 175-177.
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TY - JOUR
DO - 10.1070/MC2003v013n04ABEH001727
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001727
TI - Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine
T2 - Mendeleev Communications
AU - Lobanova, Maria Vladimirovna
AU - Bryliakov, Konstantin Petrovich
AU - Duban, Eduard Anatol'evich
AU - Talsi, Evgenii Pavlovich
PY - 2003
DA - 2003/09/02
PB - Mendeleev Communications
SP - 175-177
IS - 4
VL - 13
ER -
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@article{2003_Lobanova,
author = {Maria Vladimirovna Lobanova and Konstantin Petrovich Bryliakov and Eduard Anatol'evich Duban and Evgenii Pavlovich Talsi},
title = {Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001727},
number = {4},
pages = {175--177},
doi = {10.1070/MC2003v013n04ABEH001727}
}
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Lobanova, Maria Vladimirovna, et al. “Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine.” Mendeleev Communications, vol. 13, no. 4, Sep. 2003, pp. 175-177. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n04ABEH001727.

Abstract

Quantitative data on the stability and reactivity of the peroxidic intermediates [FeIII(TPA)(OOH)L](ClO4)2 and [FeIII(TPA)-(OOBut)L](ClO4)2 [TPA = tris(2-pyridylmethyl)amine; L = MeCN, H2O, MeOH and Py] were obtained for the first time.

References

1.
FUNCTIONAL MODELS OF NON-HEME DIIRON ENZYMES
Fontecave M., Ménage S., Duboc-Toia C.
Coordination Chemistry Reviews, 1998
3.
Biomimetic nonheme iron catalysts for alkane hydroxylation
Costas M., Chen K., Que L.
Coordination Chemistry Reviews, 2000
4.
Electronic Structure of Activated Bleomycin:  Oxygen Intermediates in Heme versus Non-Heme Iron
Neese F., Zaleski J.M., Loeb Zaleski K., Solomon E.I.
Journal of the American Chemical Society, 2000
5.
H2O2-Dependent Fe-Catalyzed Oxidations: Control of the Active Species
Mekmouche Y., Ménage S., Toia-Duboc C., Fontecave M., Galey J., Lebrun C., Pécaut J.
Angewandte Chemie - International Edition, 2001
9.
The selective functionalization of saturated hydrocarbons: Gif chemistry
Barton D.H., Doller D.
Accounts of Chemical Research, 1992
12.
Hypersensitive radical probe studies of Gif oxidations
Newcomb M., Simakov P.A., Park S.
Tetrahedron Letters, 1996
14.
[FeIII(PMA)]2+:  A Mononuclear Non-Heme Iron Complex That Catalyzes Alkane Oxidation
Nguyen C., Guajardo R.J., Mascharak P.K.
Inorganic Chemistry, 1996
15.
Stereospecific Alkane Hydroxylation with H2O2 Catalyzed by an Iron(II)−Tris(2-pyridylmethyl)amine Complex
Kim C., Chen K., Kim J., Que L.
Journal of the American Chemical Society, 1997
16.
Raman Evidence for a Weakened O−O Bond in Mononuclear Low-Spin Iron(III)−Hydroperoxides
Ho R.Y., Roelfes G., Feringa B.L., Que L.
Journal of the American Chemical Society, 1998
17.
Nonheme Iron Centers in Oxygen Activation: Characterization of an Iron(III) Hydroperoxide Intermediate
Lubben M., Meetsma A., Wilkinson E.C., Feringa B., Que L.
Angewandte Chemie International Edition in English, 1995
18.
Olefin Cis-Dihydroxylation versus Epoxidation by Non-Heme Iron Catalysts:  Two Faces of an FeIII−OOH Coin
Chen K., Costas M., Kim J., Tipton A.K., Que L.
Journal of the American Chemical Society, 2002
19.
High conversion of olefins to cis-diols by non-heme iron catalysts and H2O2
Ryu J.Y., Kim J., Costas M., Chen K., Nam W., Que Jr. L.
Chemical Communications, 2002
21.
Activated bleomycin. A transient complex of drug, iron, and oxygen that degrades DNA.
Burger R.M., Peisach J., Horwitz S.B.
Journal of Biological Chemistry, 1981
22.
A Putative Monooxygenase Mimic Which Functions via Well-Disguised Free Radical Chemistry1
MacFaul P.A., Ingold K.U., Wayner D.D., Que L.
Journal of the American Chemical Society, 1997
23.
Sulfide Oxidation by Hydrogen Peroxide Catalyzed by Iron Complexes: Two Metal Centers Are Better Than One
Mekmouche Y., Hummel H., Ho R.Y., Que, Jr. L., Schünemann V., Thomas F., Trautwein A.X., Lebrun C., Gorgy K., Leprêtre J., Collomb M., Deronzier A., Fontecave M., Ménage S., et. al.
Chemistry - A European Journal, 2002
24.
Electronic Structure and Reactivity of Low-Spin Fe(III)−Hydroperoxo Complexes:  Comparison to Activated Bleomycin
Lehnert N., Neese F., Ho R.Y., Que, L., Solomon E.I.
Journal of the American Chemical Society, 2002
25.
10.1070/MC2003v013n04ABEH001727_bib25
Shubin
Zh. Strukt. Khim., 1989