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Spontaneous resolution of a non-degenerate donor—acceptor [2]catenane

Ermitas Alcalde 1
Ermitas Alcalde
, 
Lluïsa Pérez-García 1
Lluïsa Pérez-García
, 
Susana Ramos 1
Susana Ramos
, 
J Fraser Stoddart 2
J Fraser Stoddart
, 
Scott A Vignon 2
Scott A Vignon
, 
Andrew J.P. White 3
Andrew J.P. White
, 
David J Williams 3
David J Williams
10.1070/MC2003v013n03ABEH001809
Published 2003-07-11
Communication , Volume 13, Issue 3, 100-102
14
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Alcalde E. et al. Spontaneous resolution of a non-degenerate donor—acceptor [2]catenane // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 100-102.
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Alcalde E., Pérez-García L., Ramos S., Stoddart J. F., Vignon S. A., White A. J., Williams D. J. Spontaneous resolution of a non-degenerate donor—acceptor [2]catenane // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 100-102.
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TY - JOUR
DO - 10.1070/MC2003v013n03ABEH001809
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001809
TI - Spontaneous resolution of a non-degenerate donor—acceptor [2]catenane
T2 - Mendeleev Communications
AU - Alcalde, Ermitas
AU - Pérez-García, Lluïsa
AU - Ramos, Susana
AU - Stoddart, J Fraser
AU - Vignon, Scott A
AU - White, Andrew J.P.
AU - Williams, David J
PY - 2003
DA - 2003/07/11
PB - Mendeleev Communications
SP - 100-102
IS - 3
VL - 13
ER -
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@article{2003_Alcalde,
author = {Ermitas Alcalde and Lluïsa Pérez-García and Susana Ramos and J Fraser Stoddart and Scott A Vignon and Andrew J.P. White and David J Williams},
title = {Spontaneous resolution of a non-degenerate donor—acceptor [2]catenane},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001809},
number = {3},
pages = {100--102},
doi = {10.1070/MC2003v013n03ABEH001809}
}
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Alcalde, Ermitas, et al. “Spontaneous resolution of a non-degenerate donor—acceptor [2]catenane.” Mendeleev Communications, vol. 13, no. 3, Jul. 2003, pp. 100-102. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001809.

Abstract

The incorporation of a 3,5-bis(methylene)-1H-1,2,4-triazole unit into the macrocyclic polyether component of a donor–acceptor [2]catenane induces selectivity in the isomerization processes operating within the molecule, since it exists both in solution and in the solid state as only one of two possible translational isomers, and, upon crystallisation, undergoes spontaneous resolution under racemizing conditions.

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