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Chiral switching and fast reversible molecular movement phenomena in crystals

Shinya Hirano 1
Shinya Hirano
, 
Kazuhiro Yoshizawa 1
Kazuhiro Yoshizawa
, 
Shinji Toyota 1
Shinji Toyota
, 
Fumio Toda 1
Fumio Toda
, 
Zofia Urbanczyk-Lipkowska 2
Zofia Urbanczyk-Lipkowska
10.1070/MC2003v013n03ABEH001808
Published 2003-07-11
Communication , Volume 13, Issue 3, 141-144
7
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Hirano S. et al. Chiral switching and fast reversible molecular movement phenomena in crystals // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 141-144.
GOST all authors (up to 50) Copy
Hirano S., Yoshizawa K., Toyota S., Toda F., Urbanczyk-Lipkowska Z. Chiral switching and fast reversible molecular movement phenomena in crystals // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 141-144.
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TY - JOUR
DO - 10.1070/MC2003v013n03ABEH001808
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001808
TI - Chiral switching and fast reversible molecular movement phenomena in crystals
T2 - Mendeleev Communications
AU - Hirano, Shinya
AU - Yoshizawa, Kazuhiro
AU - Toyota, Shinji
AU - Toda, Fumio
AU - Urbanczyk-Lipkowska, Zofia
PY - 2003
DA - 2003/07/11
PB - Mendeleev Communications
SP - 141-144
IS - 3
VL - 13
ER -
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@article{2003_Hirano,
author = {Shinya Hirano and Kazuhiro Yoshizawa and Shinji Toyota and Fumio Toda and Zofia Urbanczyk-Lipkowska},
title = {Chiral switching and fast reversible molecular movement phenomena in crystals},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001808},
number = {3},
pages = {141--144},
doi = {10.1070/MC2003v013n03ABEH001808}
}
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Hirano, Shinya, et al. “Chiral switching and fast reversible molecular movement phenomena in crystals.” Mendeleev Communications, vol. 13, no. 3, Jul. 2003, pp. 141-144. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001808.

Abstract

As found using FTIR, powder diffraction and CD spectrometry, in reversible inclusion complexation between crystalline hosts and gaseous guests, host molecules showed novel chiral switching phenomena: fast and reversible molecular displacement, rotation around the C–C bond, and switching between different hydrogen-bonding patterns.

References

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Solvent-Free Organic Synthesis
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Formation of racemic compound crystals by mixing of two enantiomeric crystals in the solid state. Liquid transport of molecules from crystal to crystal
Toda F., Tanaka K., Miyamoto H., Koshima H., Miyahara I., Hirotsu K.
Journal of the Chemical Society Perkin Transactions 2, 1997