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Pasteur-like resolution of quasi-racemates in solid and gas phases

Remir Grigorevich Kostyanovsky 1
Remir Grigorevich Kostyanovsky
, 
Eugene Nikolaevich Nikolaev 2
Eugene Nikolaevich Nikolaev
, 
Oleg Nikolaevich Kharybin 2
Oleg Nikolaevich Kharybin
, 
Gulnara Konstantinovna Kadorkina 1
Gulnara Konstantinovna Kadorkina
, 
Vasily Remirovich Kostyanovsky 1
Vasily Remirovich Kostyanovsky
10.1070/MC2003v013n03ABEH001801
Published 2003-07-11
Communication , Volume 13, Issue 3, 97-99
4
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Kostyanovsky R. G. et al. Pasteur-like resolution of quasi-racemates in solid and gas phases // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 97-99.
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Kostyanovsky R. G., Nikolaev E. N., Kharybin O. N., Kadorkina G. K., Kostyanovsky V. R. Pasteur-like resolution of quasi-racemates in solid and gas phases // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 97-99.
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TY - JOUR
DO - 10.1070/MC2003v013n03ABEH001801
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001801
TI - Pasteur-like resolution of quasi-racemates in solid and gas phases
T2 - Mendeleev Communications
AU - Kostyanovsky, Remir Grigorevich
AU - Nikolaev, Eugene Nikolaevich
AU - Kharybin, Oleg Nikolaevich
AU - Kadorkina, Gulnara Konstantinovna
AU - Kostyanovsky, Vasily Remirovich
PY - 2003
DA - 2003/07/11
PB - Mendeleev Communications
SP - 97-99
IS - 3
VL - 13
ER -
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@article{2003_Kostyanovsky,
author = {Remir Grigorevich Kostyanovsky and Eugene Nikolaevich Nikolaev and Oleg Nikolaevich Kharybin and Gulnara Konstantinovna Kadorkina and Vasily Remirovich Kostyanovsky},
title = {Pasteur-like resolution of quasi-racemates in solid and gas phases},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001801},
number = {3},
pages = {97--99},
doi = {10.1070/MC2003v013n03ABEH001801}
}
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Kostyanovsky, Remir Grigorevich, et al. “Pasteur-like resolution of quasi-racemates in solid and gas phases.” Mendeleev Communications, vol. 13, no. 3, Jul. 2003, pp. 97-99. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001801.

Abstract

Isotopomeric quasi-racemates (IQR), i.e., 1:1 mixtures of enantiomers one of which contains an isotopic label, can undergo crystallisation as conglomerates or true quasi-racemates. In the former case, each single crystal contains, predominantly or exclusively, either labelled or non-labelled enantiomers, whereas in the latter case, it contains both enantiomers (1:1). If solution sputtering is used to ionise quasi-racemates, the formation of homochiral protonated and metallated enantiomers and their homochiral oligomers in the gas phase is detected in ion cyclotron resonance (ICR) mass spectra; these compounds differ in their m/z values; hence, Pasteur-like ‘manual sorting’ can be employed to catch them successively in the ion trap of the spectrometer.

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