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The first chiral derivatives of 1-boraadamantane

Mikhail Evguen'evich Gurskii 1
Mikhail Evguen'evich Gurskii
, 
Vladimir Aleksandrovich Ponomarev 1
Vladimir Aleksandrovich Ponomarev
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
, 
Mikhail Yuvenal'evich Antipin 2
Mikhail Yuvenal'evich Antipin
, 
Philippe Renaud 3
Philippe Renaud
, 
Yurii Nikolaevich Bubnov 2
Yurii Nikolaevich Bubnov
10.1070/MC2003v013n03ABEH001791
Published 2003-07-11
Communication , Volume 13, Issue 3, 121-123
5
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Gurskii M. E. et al. The first chiral derivatives of 1-boraadamantane // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 121-123.
GOST all authors (up to 50) Copy
Gurskii M. E., Ponomarev V. A., Lyssenko K. A., Antipin M. Y., Renaud P., Bubnov Y. N. The first chiral derivatives of 1-boraadamantane // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 121-123.
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TY - JOUR
DO - 10.1070/MC2003v013n03ABEH001791
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001791
TI - The first chiral derivatives of 1-boraadamantane
T2 - Mendeleev Communications
AU - Gurskii, Mikhail Evguen'evich
AU - Ponomarev, Vladimir Aleksandrovich
AU - Lyssenko, Konstantin Alexandrovich
AU - Antipin, Mikhail Yuvenal'evich
AU - Renaud, Philippe
AU - Bubnov, Yurii Nikolaevich
PY - 2003
DA - 2003/07/11
PB - Mendeleev Communications
SP - 121-123
IS - 3
VL - 13
ER -
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@article{2003_Gurskii,
author = {Mikhail Evguen'evich Gurskii and Vladimir Aleksandrovich Ponomarev and Konstantin Alexandrovich Lyssenko and Mikhail Yuvenal'evich Antipin and Philippe Renaud and Yurii Nikolaevich Bubnov},
title = {The first chiral derivatives of 1-boraadamantane},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001791},
number = {3},
pages = {121--123},
doi = {10.1070/MC2003v013n03ABEH001791}
}
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Gurskii, Mikhail Evguen'evich, et al. “The first chiral derivatives of 1-boraadamantane.” Mendeleev Communications, vol. 13, no. 3, Jul. 2003, pp. 121-123. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001791.

Abstract

Both (S)-(+)- [(S)-5] and (R)-(−)-2-methyl-1-boraadamantane [(R)-5] were isolated in 96% and 92% ee, respectively, by the crystallization of corresponding (S)-(−)- and (R)-(+)-phenylethylamine adducts from hexane and transformed into optically active 1-hydroxy-2-methyladamantanes by the carbonylation–oxidation sequence.

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