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Crystal structure and magnetic properties of novel chiral nitroxides existing as racemic conglomerates

Naohiko Ikuma 1
Naohiko Ikuma
, 
Rui Tamura 1
Rui Tamura
, 
Satoshi Shimono 1
Satoshi Shimono
, 
Naoyuki Kawame 1
Naoyuki Kawame
, 
Osamu Tamada 1
Osamu Tamada
, 
Naoko Sakai 1
Naoko Sakai
, 
Jun Yamauchi 1
Jun Yamauchi
, 
Yokio Yamamoto 1
Yokio Yamamoto
10.1070/MC2003v013n03ABEH001787
Published 2003-07-11
Communication , Volume 13, Issue 3, 109-111
16
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Ikuma N. et al. Crystal structure and magnetic properties of novel chiral nitroxides existing as racemic conglomerates // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 109-111.
GOST all authors (up to 50) Copy
Ikuma N., Tamura R., Shimono S., Kawame N., Tamada O., Sakai N., Yamauchi J., Yamamoto Y. Crystal structure and magnetic properties of novel chiral nitroxides existing as racemic conglomerates // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 109-111.
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TY - JOUR
DO - 10.1070/MC2003v013n03ABEH001787
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001787
TI - Crystal structure and magnetic properties of novel chiral nitroxides existing as racemic conglomerates
T2 - Mendeleev Communications
AU - Ikuma, Naohiko
AU - Tamura, Rui
AU - Shimono, Satoshi
AU - Kawame, Naoyuki
AU - Tamada, Osamu
AU - Sakai, Naoko
AU - Yamauchi, Jun
AU - Yamamoto, Yokio
PY - 2003
DA - 2003/07/11
PB - Mendeleev Communications
SP - 109-111
IS - 3
VL - 13
ER -
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@article{2003_Ikuma,
author = {Naohiko Ikuma and Rui Tamura and Satoshi Shimono and Naoyuki Kawame and Osamu Tamada and Naoko Sakai and Jun Yamauchi and Yokio Yamamoto},
title = {Crystal structure and magnetic properties of novel chiral nitroxides existing as racemic conglomerates},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001787},
number = {3},
pages = {109--111},
doi = {10.1070/MC2003v013n03ABEH001787}
}
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Ikuma, Naohiko, et al. “Crystal structure and magnetic properties of novel chiral nitroxides existing as racemic conglomerates.” Mendeleev Communications, vol. 13, no. 3, Jul. 2003, pp. 109-111. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001787.

Abstract

Racemic samples of novel chiral cyclic nitroxides 2-(4-hydroxyphenyl)-2,5,5-trimethylpyrrolidine-1-oxy 1, trans-2-(4-hydroxyphenyl)-2,5-dimethyl-5-phenylpyrrolidine-1-oxy 2 and trans-2,5-bis(4-hydroxyphenyl)-2,5-dimethylpyrrolidine-1-oxy 3 having 4-hydroxyphenyl groups on the stereogenic centres adjacent to the NO radical moiety have been found to exist as racemic conglomerates in the crystalline state, and the origin of the conglomerate formation has been studied by X-ray crystallographic analysis and magnetic susceptibility measurements.

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