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Induction of chirality in donor–acceptor spiro compounds

Marcin Kwit 1
Marcin Kwit
, 
Jacek Gawronski 1
Jacek Gawronski
10.1070/MC2003v013n03ABEH001756
Published 2003-07-11
Communication , Volume 13, Issue 3, 139-140
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Kwit M., Gawronski J. Induction of chirality in donor–acceptor spiro compounds // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 139-140.
GOST all authors (up to 50) Copy
Kwit M., Gawronski J. Induction of chirality in donor–acceptor spiro compounds // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 139-140.
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TY - JOUR
DO - 10.1070/MC2003v013n03ABEH001756
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001756
TI - Induction of chirality in donor–acceptor spiro compounds
T2 - Mendeleev Communications
AU - Kwit, Marcin
AU - Gawronski, Jacek
PY - 2003
DA - 2003/07/11
PB - Mendeleev Communications
SP - 139-140
IS - 3
VL - 13
ER -
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@article{2003_Kwit,
author = {Marcin Kwit and Jacek Gawronski},
title = {Induction of chirality in donor–acceptor spiro compounds},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001756},
number = {3},
pages = {139--140},
doi = {10.1070/MC2003v013n03ABEH001756}
}
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MLA Copy
Kwit, Marcin, and Jacek Gawronski. “Induction of chirality in donor–acceptor spiro compounds.” Mendeleev Communications, vol. 13, no. 3, Jul. 2003, pp. 139-140. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001756.

Abstract

HOMO–LUMO transitions observed in chiral donor–acceptor spiro compounds 1 and 2 are of the n–π* type, based on the high dissymmetry factor Δϵ/ϵ ≅ 10–2 determined from their CD and absorption spectra.

References

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Donor‐Acceptor Spiro‐Compounds — Syntheses, Structures, and Electronic Properties
Gleiter R., Hoffmann H., Irngartinger H., Nixdorf M.
Chemische Berichte, 1994
2.
Spiroconjugated intramolecular charge-transfer dyes
Maslak P., Chopra A.
Journal of the American Chemical Society, 1993
3.
Optical Properties of Spiroconjugated Charge-Transfer Dyes
Maslak P., Chopra A., Moylan C.R., Wortmann R., Lebus S., Rheingold A.L., Yap G.P.
Journal of the American Chemical Society, 1996