Home / Publications / Nitrogen chirality via the sterical veto of N inversion

Nitrogen chirality via the sterical veto of N inversion

Sergei Valer'evich Usachev 1
Sergei Valer'evich Usachev
, 
Grigorii Alekseevich Nikiforov 2
Grigorii Alekseevich Nikiforov
, 
Yurii Andreevich Strelenko 3
Yurii Andreevich Strelenko
, 
Ivan Ivanovich Chervin 1
Ivan Ivanovich Chervin
, 
Konstantin Alexandrovich Lyssenko 4
Konstantin Alexandrovich Lyssenko
, 
Remir Grigorevich Kostyanovsky 1
Remir Grigorevich Kostyanovsky
10.1070/MC2003v013n03ABEH001751
Published 2003-07-11
Communication , Volume 13, Issue 3, 136-139
7
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Usachev S. V. et al. Nitrogen chirality via the sterical veto of N inversion // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 136-139.
GOST all authors (up to 50) Copy
Usachev S. V., Nikiforov G. A., Strelenko Y. A., Chervin I. I., Lyssenko K. A., Kostyanovsky R. G. Nitrogen chirality via the sterical veto of N inversion // Mendeleev Communications. 2003. Vol. 13. No. 3. pp. 136-139.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2003v013n03ABEH001751
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001751
TI - Nitrogen chirality via the sterical veto of N inversion
T2 - Mendeleev Communications
AU - Usachev, Sergei Valer'evich
AU - Nikiforov, Grigorii Alekseevich
AU - Strelenko, Yurii Andreevich
AU - Chervin, Ivan Ivanovich
AU - Lyssenko, Konstantin Alexandrovich
AU - Kostyanovsky, Remir Grigorevich
PY - 2003
DA - 2003/07/11
PB - Mendeleev Communications
SP - 136-139
IS - 3
VL - 13
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2003_Usachev,
author = {Sergei Valer'evich Usachev and Grigorii Alekseevich Nikiforov and Yurii Andreevich Strelenko and Ivan Ivanovich Chervin and Konstantin Alexandrovich Lyssenko and Remir Grigorevich Kostyanovsky},
title = {Nitrogen chirality via the sterical veto of N inversion},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001751},
number = {3},
pages = {136--139},
doi = {10.1070/MC2003v013n03ABEH001751}
}
MLA
Cite this
MLA Copy
Usachev, Sergei Valer'evich, et al. “Nitrogen chirality via the sterical veto of N inversion.” Mendeleev Communications, vol. 13, no. 3, Jul. 2003, pp. 136-139. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n03ABEH001751.

Abstract

Novel cyclic hydrazines 4–8 with sterically hindered (4, 6, 7) or arrested (5, 8) nitrogen inversion were synthesised; pyrazolydine 5 was separated into enantiomers by chiral chromatography; the crystal structures of salts 5a and 5b were studied by X-raydiffraction analysis.

References

1.
Usachev S.V., Nikiforov G.A., Strelenko Y.A., Belyakov P.A., Chervin I.I., Kostyanovsky R.G.
Mendeleev Communications, 2002
2.
Saturated five-membered heterocyclics, III.: Conversion of 1,3,4-oxadiazolidines into 1,2,4-triazolidines
Zwanenburg B., Weening W.E., Strating J.
Recueil des Travaux Chimiques des Pays-Bas, 2010
3.
Saturated five membered heterocyclics, II: Preparation of 1,3,4-oxadiazolidines
Zwanenburg B., Weening W.E., Strating J.
Recueil des Travaux Chimiques des Pays-Bas, 2010
4.
Pronounced Steric Hindrance for Nitrogen Inversion in 1,3,4-Oxadiazolidines
Kostyanovsky R., Kadorkina G., Kostyanovsky V., Schurig V., Trapp O.
Angewandte Chemie - International Edition, 2000
5.
Thiadiaziridine 1,1-dioxides: synthesis and chemistry
Timberlake J.W., Alender J., Garner A.W., Hodges M.L., Ozmeral C., Szilagyi S., Jacobus J.O.
Journal of Organic Chemistry, 1981
6.
The Behavior of Aliphatic Aldehydes in the Leuckart-Wallach Reaction
deBenneville P.L., Macartney J.H.
Journal of the American Chemical Society, 1950
10.
Diaziridinones (2,3-diazacyclopropanones). II. Synthesis, properties, and reactions
Greene F.D., Stowell J.C., Bergmark W.R.
Journal of Organic Chemistry, 1969
11.
Kostyanovsky R.G., Kadorkina G.K., Voznesensky V.N., Chervin I.I., Antipin M.Y., Lyssenko K.A., Vorontzov E.V., Bakhmutov V.I., Rademacher P.
Mendeleev Communications, 1996