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Intramolecular H-bonds in the crystal of tetraacetylethane: 3c-4e interaction or a dynamic disorder?

Konstantin Alexandrovich Lyssenko 1
Konstantin Alexandrovich Lyssenko
, 
Denis Victorovich Lyubetsky 1
Denis Victorovich Lyubetsky
, 
Mikhail Yuvenal'evich Antipin 1
Mikhail Yuvenal'evich Antipin
10.1070/MC2003v013n02ABEH001696
Published 2003-04-28
Communication , Volume 13, Issue 2, 60-62
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Lyssenko K. A., Lyubetsky D. V., Antipin M. Y. Intramolecular H-bonds in the crystal of tetraacetylethane: 3c-4e interaction or a dynamic disorder? // Mendeleev Communications. 2003. Vol. 13. No. 2. pp. 60-62.
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Lyssenko K. A., Lyubetsky D. V., Antipin M. Y. Intramolecular H-bonds in the crystal of tetraacetylethane: 3c-4e interaction or a dynamic disorder? // Mendeleev Communications. 2003. Vol. 13. No. 2. pp. 60-62.
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TY - JOUR
DO - 10.1070/MC2003v013n02ABEH001696
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n02ABEH001696
TI - Intramolecular H-bonds in the crystal of tetraacetylethane: 3c-4e interaction or a dynamic disorder?
T2 - Mendeleev Communications
AU - Lyssenko, Konstantin Alexandrovich
AU - Lyubetsky, Denis Victorovich
AU - Antipin, Mikhail Yuvenal'evich
PY - 2003
DA - 2003/04/28
PB - Mendeleev Communications
SP - 60-62
IS - 2
VL - 13
ER -
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@article{2003_Lyssenko,
author = {Konstantin Alexandrovich Lyssenko and Denis Victorovich Lyubetsky and Mikhail Yuvenal'evich Antipin},
title = {Intramolecular H-bonds in the crystal of tetraacetylethane: 3c-4e interaction or a dynamic disorder?},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n02ABEH001696},
number = {2},
pages = {60--62},
doi = {10.1070/MC2003v013n02ABEH001696}
}
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Lyssenko, Konstantin Alexandrovich, et al. “Intramolecular H-bonds in the crystal of tetraacetylethane: 3c-4e interaction or a dynamic disorder?.” Mendeleev Communications, vol. 13, no. 2, Apr. 2003, pp. 60-62. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n02ABEH001696.

Abstract

The analysis of the experimental electron density function and anisotropic displacement parameters in tetraacetylethane has revealed that the intramolecular O–H···O bond corresponds to the intermediate type of interatomic interactions and that the variation of the C–O and C–C bond lengths with temperature (110–298 K) is the result of the dynamic disorder (superposition of tautomers) due to interatomic C–H···O contacts.

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