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Unusual catalytic effect of halide anions in the protolytic dissociation of indium(III) octaphenyltetraazaporphyrins

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10.1070/MC2003v013n01ABEH001704
Published 2003-03-04
Communication , Volume 13, Issue 1, 17-18
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Ivanova S. S., Stuzhin P. A. Unusual catalytic effect of halide anions in the protolytic dissociation of indium(III) octaphenyltetraazaporphyrins // Mendeleev Communications. 2003. Vol. 13. No. 1. pp. 17-18.
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Ivanova S. S., Stuzhin P. A. Unusual catalytic effect of halide anions in the protolytic dissociation of indium(III) octaphenyltetraazaporphyrins // Mendeleev Communications. 2003. Vol. 13. No. 1. pp. 17-18.
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TY - JOUR
DO - 10.1070/MC2003v013n01ABEH001704
UR - https://mendcomm.colab.ws/publications/10.1070/MC2003v013n01ABEH001704
TI - Unusual catalytic effect of halide anions in the protolytic dissociation of indium(III) octaphenyltetraazaporphyrins
T2 - Mendeleev Communications
AU - Ivanova, Svetlana Sergeevna
AU - Stuzhin, Pavel Anatolievich
PY - 2003
DA - 2003/03/04
PB - Mendeleev Communications
SP - 17-18
IS - 1
VL - 13
ER -
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@article{2003_Ivanova,
author = {Svetlana Sergeevna Ivanova and Pavel Anatolievich Stuzhin},
title = {Unusual catalytic effect of halide anions in the protolytic dissociation of indium(III) octaphenyltetraazaporphyrins},
journal = {Mendeleev Communications},
year = {2003},
volume = {13},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2003v013n01ABEH001704},
number = {1},
pages = {17--18},
doi = {10.1070/MC2003v013n01ABEH001704}
}
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Ivanova, Svetlana Sergeevna, and Pavel Anatolievich Stuzhin. “Unusual catalytic effect of halide anions in the protolytic dissociation of indium(III) octaphenyltetraazaporphyrins.” Mendeleev Communications, vol. 13, no. 1, Mar. 2003, pp. 17-18. https://mendcomm.colab.ws/publications/10.1070/MC2003v013n01ABEH001704.

Abstract

Chloro(octaphenyltetraazaporphyrinato)indium(III) [(Cl)InOPTAP] dissociates easily in slightly acidified dichloromethane solutions (0.001–0.01 M CF3COOH) after addition of tetraethylammonium chloride; the observed catalytic effect of chloride anions is due to their additional cis-coordination to the In atom with formation of the dianionic complex [(Cl)3InOPTAP]2–.

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