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Iminopinacol coupling with lithium: electron-transfer mediators

Electron Aleksandrovich Mistryukov 1
Electron Aleksandrovich Mistryukov
10.1070/MC2002v012n06ABEH001617
Published 2002-01-15
Communication , Volume 12, Issue 6, 230-231
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Mistryukov E. A. Iminopinacol coupling with lithium: electron-transfer mediators // Mendeleev Communications. 2002. Vol. 12. No. 6. pp. 230-231.
GOST all authors (up to 50) Copy
Mistryukov E. A. Iminopinacol coupling with lithium: electron-transfer mediators // Mendeleev Communications. 2002. Vol. 12. No. 6. pp. 230-231.
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TY - JOUR
DO - 10.1070/MC2002v012n06ABEH001617
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n06ABEH001617
TI - Iminopinacol coupling with lithium: electron-transfer mediators
T2 - Mendeleev Communications
AU - Mistryukov, Electron Aleksandrovich
PY - 2002
DA - 2002/01/15
PB - Mendeleev Communications
SP - 230-231
IS - 6
VL - 12
ER -
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@article{2002_Mistryukov,
author = {Electron Aleksandrovich Mistryukov},
title = {Iminopinacol coupling with lithium: electron-transfer mediators},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n06ABEH001617},
number = {6},
pages = {230--231},
doi = {10.1070/MC2002v012n06ABEH001617}
}
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Mistryukov, Electron Aleksandrovich. “Iminopinacol coupling with lithium: electron-transfer mediators.” Mendeleev Communications, vol. 12, no. 6, Jan. 2002, pp. 230-231. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n06ABEH001617.

Abstract

The addition of tert-butyl borate or ethyl formate to N-alkylbenzalimines directs the reaction pathway from the Birch reduction to the pinacol-type coupling with lithium in THF; an analogous reaction with a dimethylimmonium salt requires a trace titanium catalyst as the electron-transfer mediator.

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10.1070/MC2002v012n06ABEH001617_bib10
Aleexakis
Synlett, 1998