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First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds

Irena Sergeevna Akhrem 1
Irena Sergeevna Akhrem
, 
Lyudmila Vyacheslavovna Afanas'eva 1
Lyudmila Vyacheslavovna Afanas'eva
, 
Sergei Vladimirovich Vitt 1
Sergei Vladimirovich Vitt
, 
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
10.1070/MC2002v012n05ABEH001661
Published 2002-11-15
Communication , Volume 12, Issue 5, 180-182
8
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Akhrem I. S. et al. First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds // Mendeleev Communications. 2002. Vol. 12. No. 5. pp. 180-182.
GOST all authors (up to 50) Copy
Akhrem I. S., Afanas'eva L. V., Vitt S. V., Petrovskii P. V. First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds // Mendeleev Communications. 2002. Vol. 12. No. 5. pp. 180-182.
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TY - JOUR
DO - 10.1070/MC2002v012n05ABEH001661
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n05ABEH001661
TI - First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds
T2 - Mendeleev Communications
AU - Akhrem, Irena Sergeevna
AU - Afanas'eva, Lyudmila Vyacheslavovna
AU - Vitt, Sergei Vladimirovich
AU - Petrovskii, Pavel Vasil'evich
PY - 2002
DA - 2002/11/15
PB - Mendeleev Communications
SP - 180-182
IS - 5
VL - 12
ER -
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@article{2002_Akhrem,
author = {Irena Sergeevna Akhrem and Lyudmila Vyacheslavovna Afanas'eva and Sergei Vladimirovich Vitt and Pavel Vasil'evich Petrovskii},
title = {First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n05ABEH001661},
number = {5},
pages = {180--182},
doi = {10.1070/MC2002v012n05ABEH001661}
}
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Akhrem, Irena Sergeevna, et al. “First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds.” Mendeleev Communications, vol. 12, no. 5, Nov. 2002, pp. 180-182. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n05ABEH001661.

Abstract

The carbonylation of C6–C10 n-alkanes with CO in the presence of CBr4·2AlBr3 at –40 °C and 1 atm CO leads to the products of non-destructive carbonylation, i.e., the esters of tertiary carboxylic acids, R1C(Me)2COOR and R2(Et)C(Me)COOR, after the workup of reaction mixtures with ROH.

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