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η6-Arene–tricarbonylchromium complexes in the syntheses of trans-resveratrol and pinostilbene

Konstantin Evgen'evich Polunin 1
Konstantin Evgen'evich Polunin
,  , 
Hans Guenther Schmalz 2
Hans Guenther Schmalz
10.1070/MC2002v012n05ABEH001616
Published 2002-11-15
Communication , Volume 12, Issue 5, 178-180
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Polunin K. E., Polunina I. A., Schmalz H. G. η6-Arene–tricarbonylchromium complexes in the syntheses of trans-resveratrol and pinostilbene // Mendeleev Communications. 2002. Vol. 12. No. 5. pp. 178-180.
GOST all authors (up to 50) Copy
Polunin K. E., Polunina I. A., Schmalz H. G. η6-Arene–tricarbonylchromium complexes in the syntheses of trans-resveratrol and pinostilbene // Mendeleev Communications. 2002. Vol. 12. No. 5. pp. 178-180.
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TY - JOUR
DO - 10.1070/MC2002v012n05ABEH001616
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n05ABEH001616
TI - η6-Arene–tricarbonylchromium complexes in the syntheses of trans-resveratrol and pinostilbene
T2 - Mendeleev Communications
AU - Polunin, Konstantin Evgen'evich
AU - Polunina, Irina Alexandrovna
AU - Schmalz, Hans Guenther
PY - 2002
DA - 2002/11/15
PB - Mendeleev Communications
SP - 178-180
IS - 5
VL - 12
ER -
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@article{2002_Polunin,
author = {Konstantin Evgen'evich Polunin and Irina Alexandrovna Polunina and Hans Guenther Schmalz},
title = {η6-Arene–tricarbonylchromium complexes in the syntheses of trans-resveratrol and pinostilbene},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n05ABEH001616},
number = {5},
pages = {178--180},
doi = {10.1070/MC2002v012n05ABEH001616}
}
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Polunin, Konstantin Evgen'evich, et al. “η6-Arene–tricarbonylchromium complexes in the syntheses of trans-resveratrol and pinostilbene.” Mendeleev Communications, vol. 12, no. 5, Nov. 2002, pp. 178-180. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n05ABEH001616.

Abstract

New syntheses of trans-resveratrol (trans-3,5,4’-trihydroxystilbene) and pinostilbene (trans-3,4’-dihydroxy-5-methoxystilbene) via nucleophilic demethylation of trimethoxystilbene were performed, whereby trans-3,5,4’-trimethoxystilbene was obtained through facilitated benzylic deprotonation of an η6-benzene-Cr(CO)3 derivative and subsequent coupling with para-anisaldehyde in an aldol-type or Wittig–Horner reaction.

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